Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary Stereocenters

Xing Ping Zeng; Zhong Yan Cao; Yu Hui Wang; Feng Zhou; Jian Zhou

doi:10.1021/acs.chemrev.6b00094

Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary Stereocenters

Xing Ping Zeng
, Zhong Yan Cao
, Yu Hui Wang
, Feng Zhou
, Jian Zhou^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Review article › peer-review

680 Scopus citations

Abstract

This Review summarizes the advances in the construction of all-carbon quaternary stereocenters via catalytic enantioselective desymmetrization of prochiral and meso-compounds, highlights the power and potential of this strategy in the total synthesis of natural products and biologically active compounds, and outlines the synthetic opportunities still available.

Original language	English
Pages (from-to)	7330-7396
Number of pages	67
Journal	Chemical Reviews
Volume	116
Issue number	12
DOIs	https://doi.org/10.1021/acs.chemrev.6b00094
State	Published - 22 Jun 2016

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10.1021/acs.chemrev.6b00094

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title = "Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary Stereocenters",

abstract = "This Review summarizes the advances in the construction of all-carbon quaternary stereocenters via catalytic enantioselective desymmetrization of prochiral and meso-compounds, highlights the power and potential of this strategy in the total synthesis of natural products and biologically active compounds, and outlines the synthetic opportunities still available.",

author = "Zeng, \{Xing Ping\} and Cao, \{Zhong Yan\} and Wang, \{Yu Hui\} and Feng Zhou and Jian Zhou",

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doi = "10.1021/acs.chemrev.6b00094",

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T1 - Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary Stereocenters

AU - Zeng, Xing Ping

AU - Cao, Zhong Yan

AU - Wang, Yu Hui

AU - Zhou, Feng

AU - Zhou, Jian

PY - 2016/6/22

Y1 - 2016/6/22

N2 - This Review summarizes the advances in the construction of all-carbon quaternary stereocenters via catalytic enantioselective desymmetrization of prochiral and meso-compounds, highlights the power and potential of this strategy in the total synthesis of natural products and biologically active compounds, and outlines the synthetic opportunities still available.

AB - This Review summarizes the advances in the construction of all-carbon quaternary stereocenters via catalytic enantioselective desymmetrization of prochiral and meso-compounds, highlights the power and potential of this strategy in the total synthesis of natural products and biologically active compounds, and outlines the synthetic opportunities still available.

UR - https://www.scopus.com/pages/publications/84976263012

U2 - 10.1021/acs.chemrev.6b00094

DO - 10.1021/acs.chemrev.6b00094

M3 - 文献综述

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SP - 7330

EP - 7396

JO - Chemical Reviews

JF - Chemical Reviews

IS - 12

ER -

Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary Stereocenters

Abstract

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