Catalytic Enantioselective Construction of Sulfur-Containing Tetrasubstituted Carbon Stereocenters

Jin Sheng Yu; Hong Mei Huang; Pei Gang Ding; Xiao Si Hu; Feng Zhou; Jian Zhou

doi:10.1021/acscatal.6b01496

Catalytic Enantioselective Construction of Sulfur-Containing Tetrasubstituted Carbon Stereocenters

Jin Sheng Yu, Hong Mei Huang, Pei Gang Ding, Xiao Si Hu, Feng Zhou, Jian Zhou

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Review article › peer-review

130 Scopus citations

Abstract

Sulfur-containing tetrasubstituted carbon stereocenters are widely present in natural products, drugs, and biologically active compounds. Catalytic enantioselective construction of such fully substituted carbon stereocenters is a current research interest, with four major synthetic strategies being developed. This review summarizes the advances in this field, discusses in detail the advantages and limitation of each synthetic strategy, and outlines the synthetic opportunities still open for development.

Original language	English
Pages (from-to)	5319-5344
Number of pages	26
Journal	ACS Catalysis
Volume	6
Issue number	8
DOIs	https://doi.org/10.1021/acscatal.6b01496
State	Published - 5 Aug 2016

Keywords

S-containing synthons
enantioselective C'S bond-forming reactions
metal catalysis
organocatalysis
sulfur-containing tetrasubstituted carbon stereocenters

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10.1021/acscatal.6b01496

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title = "Catalytic Enantioselective Construction of Sulfur-Containing Tetrasubstituted Carbon Stereocenters",

abstract = "Sulfur-containing tetrasubstituted carbon stereocenters are widely present in natural products, drugs, and biologically active compounds. Catalytic enantioselective construction of such fully substituted carbon stereocenters is a current research interest, with four major synthetic strategies being developed. This review summarizes the advances in this field, discusses in detail the advantages and limitation of each synthetic strategy, and outlines the synthetic opportunities still open for development.",

keywords = "S-containing synthons, enantioselective C'S bond-forming reactions, metal catalysis, organocatalysis, sulfur-containing tetrasubstituted carbon stereocenters",

author = "Yu, \{Jin Sheng\} and Huang, \{Hong Mei\} and Ding, \{Pei Gang\} and Hu, \{Xiao Si\} and Feng Zhou and Jian Zhou",

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doi = "10.1021/acscatal.6b01496",

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T1 - Catalytic Enantioselective Construction of Sulfur-Containing Tetrasubstituted Carbon Stereocenters

AU - Yu, Jin Sheng

AU - Huang, Hong Mei

AU - Ding, Pei Gang

AU - Hu, Xiao Si

AU - Zhou, Feng

AU - Zhou, Jian

PY - 2016/8/5

Y1 - 2016/8/5

N2 - Sulfur-containing tetrasubstituted carbon stereocenters are widely present in natural products, drugs, and biologically active compounds. Catalytic enantioselective construction of such fully substituted carbon stereocenters is a current research interest, with four major synthetic strategies being developed. This review summarizes the advances in this field, discusses in detail the advantages and limitation of each synthetic strategy, and outlines the synthetic opportunities still open for development.

AB - Sulfur-containing tetrasubstituted carbon stereocenters are widely present in natural products, drugs, and biologically active compounds. Catalytic enantioselective construction of such fully substituted carbon stereocenters is a current research interest, with four major synthetic strategies being developed. This review summarizes the advances in this field, discusses in detail the advantages and limitation of each synthetic strategy, and outlines the synthetic opportunities still open for development.

KW - S-containing synthons

KW - enantioselective C'S bond-forming reactions

KW - metal catalysis

KW - organocatalysis

KW - sulfur-containing tetrasubstituted carbon stereocenters

UR - https://www.scopus.com/pages/publications/84981295175

U2 - 10.1021/acscatal.6b01496

DO - 10.1021/acscatal.6b01496

M3 - 文献综述

AN - SCOPUS:84981295175

SN - 2155-5435

VL - 6

SP - 5319

EP - 5344

JO - ACS Catalysis

JF - ACS Catalysis

IS - 8

ER -

Catalytic Enantioselective Construction of Sulfur-Containing Tetrasubstituted Carbon Stereocenters

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Keywords

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