Catalytic Asymmetric Isomerization of (Homo)Allylic Alcohols: Recent Advances and Challenges

Xue Xin Zhang; Ying Zhang; Ling Liao; Yang Gao; Heng E.M. Su; Jin Sheng Yu

doi:10.1002/cctc.202200126

Catalytic Asymmetric Isomerization of (Homo)Allylic Alcohols: Recent Advances and Challenges

Xue Xin Zhang
, Ying Zhang
, Ling Liao
, Yang Gao
, Heng E.M. Su^*
, Jin Sheng Yu^*

^*Corresponding author for this work

East China Normal University
Synergetica. Inc.
Hainan Normal University

Research output: Contribution to journal › Review article › peer-review

22 Scopus citations

Abstract

Catalytic asymmetric isomerization of allylic or homoallylic alcohols into synthetically useful carbonyl compounds is a redox-neutral and 100 % atom-economic transformation, which is of great interest and has gained increasing attention from both academic and industry. This minireview summarizes the advances in catalytic enantioselective isomerization and it involved tandem reactions over the past five years, also discusses their advantages and limitations, and expounds the synthetic chances still open for further development.

Original language	English
Article number	e202200126
Journal	ChemCatChem
Volume	14
Issue number	11
DOIs	https://doi.org/10.1002/cctc.202200126
State	Published - 8 Jun 2022

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 10 Reduced Inequalities

Keywords

Allylic alcohols
Asymmetric isomerization
Organocatalysis
Tandem reaction
Transition-metal catalysis

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10.1002/cctc.202200126

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title = "Catalytic Asymmetric Isomerization of (Homo)Allylic Alcohols: Recent Advances and Challenges",

abstract = "Catalytic asymmetric isomerization of allylic or homoallylic alcohols into synthetically useful carbonyl compounds is a redox-neutral and 100 \% atom-economic transformation, which is of great interest and has gained increasing attention from both academic and industry. This minireview summarizes the advances in catalytic enantioselective isomerization and it involved tandem reactions over the past five years, also discusses their advantages and limitations, and expounds the synthetic chances still open for further development.",

keywords = "Allylic alcohols, Asymmetric isomerization, Organocatalysis, Tandem reaction, Transition-metal catalysis",

author = "Zhang, \{Xue Xin\} and Ying Zhang and Ling Liao and Yang Gao and Su, \{Heng E.M.\} and Yu, \{Jin Sheng\}",

note = "Publisher Copyright: {\textcopyright} 2022 Wiley-VCH GmbH.",

year = "2022",

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day = "8",

doi = "10.1002/cctc.202200126",

language = "英语",

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TY - JOUR

T1 - Catalytic Asymmetric Isomerization of (Homo)Allylic Alcohols

T2 - Recent Advances and Challenges

AU - Zhang, Xue Xin

AU - Zhang, Ying

AU - Liao, Ling

AU - Gao, Yang

AU - Su, Heng E.M.

AU - Yu, Jin Sheng

PY - 2022/6/8

Y1 - 2022/6/8

N2 - Catalytic asymmetric isomerization of allylic or homoallylic alcohols into synthetically useful carbonyl compounds is a redox-neutral and 100 % atom-economic transformation, which is of great interest and has gained increasing attention from both academic and industry. This minireview summarizes the advances in catalytic enantioselective isomerization and it involved tandem reactions over the past five years, also discusses their advantages and limitations, and expounds the synthetic chances still open for further development.

AB - Catalytic asymmetric isomerization of allylic or homoallylic alcohols into synthetically useful carbonyl compounds is a redox-neutral and 100 % atom-economic transformation, which is of great interest and has gained increasing attention from both academic and industry. This minireview summarizes the advances in catalytic enantioselective isomerization and it involved tandem reactions over the past five years, also discusses their advantages and limitations, and expounds the synthetic chances still open for further development.

KW - Allylic alcohols

KW - Asymmetric isomerization

KW - Organocatalysis

KW - Tandem reaction

KW - Transition-metal catalysis

UR - https://www.scopus.com/pages/publications/85127147660

U2 - 10.1002/cctc.202200126

DO - 10.1002/cctc.202200126

M3 - 文献综述

AN - SCOPUS:85127147660

SN - 1867-3880

VL - 14

JO - ChemCatChem

JF - ChemCatChem

IS - 11

M1 - e202200126

ER -

Catalytic Asymmetric Isomerization of (Homo)Allylic Alcohols: Recent Advances and Challenges

Abstract

UN SDGs

Keywords

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