Catalytic Arylative Endo Cyclization of Gold Acetylides: Access to 3,4-Diphenyl Isoquinoline, 2,3-Diphenyl Indole, and Mesoionic Normal NHC–Gold Complex

3,4-Diphenyl isoquinoline and 2,3-diphenyl indole are readily accessed by catalytic selective bis-arylative endo cyclization of gold acetylides. The synthetic approach could be also extended to prepare six-membered mesoionic NHC complex, which could further undergo deprotonation/complexation to afford 1,3-N-heterocyclic dicarbene (NHDCs) Au₂ and Au/Ag complexes. The key vicinal diaurated alkene intermediates have been isolated and the studies on their reactivities towards coupling partners reinforce the proposed mechanisms.