Catalysis of photooxidation reactions through transformation between Cu2+ and Cu+ in TiO2-Cu-MOF composites

Chunjun Chen; Tianbin Wu; Dexin Yang; Pei Zhang; Huizhen Liu; Youdi Yang; Guanying Yang; Buxing Han

doi:10.1039/c8cc03505a

Catalysis of photooxidation reactions through transformation between Cu²⁺ and Cu⁺ in TiO₂-Cu-MOF composites

Chunjun Chen, Tianbin Wu, Dexin Yang, Pei Zhang, Huizhen Liu, Youdi Yang, Guanying Yang, Buxing Han

Chinese Academy of Sciences

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

Novel porous TiO₂@Cu₃(BTC)₂ composites, which were synthesized using ionic liquids (ILs) as solvents, exhibited excellent activity for photooxidation of styrene to 4-aryl tetralones and promoting the Glaser coupling reaction with O₂ under light irradiation. It was discovered that the transformation between Cu²⁺ and Cu⁺ was crucial for enhancing the photocatalytic performance.

Original language	English
Pages (from-to)	5984-5987
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	47
DOIs	https://doi.org/10.1039/c8cc03505a
State	Published - 2018
Externally published	Yes

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title = "Catalysis of photooxidation reactions through transformation between Cu2+ and Cu+ in TiO2-Cu-MOF composites",

abstract = "Novel porous TiO2@Cu3(BTC)2 composites, which were synthesized using ionic liquids (ILs) as solvents, exhibited excellent activity for photooxidation of styrene to 4-aryl tetralones and promoting the Glaser coupling reaction with O2 under light irradiation. It was discovered that the transformation between Cu2+ and Cu+ was crucial for enhancing the photocatalytic performance.",

author = "Chunjun Chen and Tianbin Wu and Dexin Yang and Pei Zhang and Huizhen Liu and Youdi Yang and Guanying Yang and Buxing Han",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c8cc03505a",

language = "英语",

volume = "54",

pages = "5984--5987",

journal = "Chemical Communications",

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T1 - Catalysis of photooxidation reactions through transformation between Cu2+ and Cu+ in TiO2-Cu-MOF composites

AU - Chen, Chunjun

AU - Wu, Tianbin

AU - Yang, Dexin

AU - Zhang, Pei

AU - Liu, Huizhen

AU - Yang, Youdi

AU - Yang, Guanying

AU - Han, Buxing

PY - 2018

Y1 - 2018

N2 - Novel porous TiO2@Cu3(BTC)2 composites, which were synthesized using ionic liquids (ILs) as solvents, exhibited excellent activity for photooxidation of styrene to 4-aryl tetralones and promoting the Glaser coupling reaction with O2 under light irradiation. It was discovered that the transformation between Cu2+ and Cu+ was crucial for enhancing the photocatalytic performance.

AB - Novel porous TiO2@Cu3(BTC)2 composites, which were synthesized using ionic liquids (ILs) as solvents, exhibited excellent activity for photooxidation of styrene to 4-aryl tetralones and promoting the Glaser coupling reaction with O2 under light irradiation. It was discovered that the transformation between Cu2+ and Cu+ was crucial for enhancing the photocatalytic performance.

UR - https://www.scopus.com/pages/publications/85048356002

U2 - 10.1039/c8cc03505a

DO - 10.1039/c8cc03505a

M3 - 文章

C2 - 29790501

AN - SCOPUS:85048356002

SN - 1359-7345

VL - 54

SP - 5984

EP - 5987

JO - Chemical Communications

JF - Chemical Communications

IS - 47

ER -

Catalysis of photooxidation reactions through transformation between Cu²⁺ and Cu⁺ in TiO₂-Cu-MOF composites

Abstract

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