Carboxyl group functionalized hollow microporous organic nanospheres for efficient catalysis and adsorption

Minghong Zhou; Zidong He; Tianqi Wang; Yang Xu; Wei Yu; Buyin Shi; Kun Huang

doi:10.1016/j.micromeso.2018.08.005

Carboxyl group functionalized hollow microporous organic nanospheres for efficient catalysis and adsorption

Minghong Zhou
, Zidong He
, Tianqi Wang
, Yang Xu
, Wei Yu
, Buyin Shi
, Kun Huang^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Carboxyl group functionalized hollow microporous organic nanospheres (HMONs-COOH) were successfully synthesized by hyper-crosslinking reaction between polylactide-b-polystyrene (PLA-b-PS) diblock copolymers and 2,4,6-tris(bromomethyl)mesitylene as well as subsequent alkaline KMnO₄ oxidation. The synthesized HMONs-COOH possess the high special surface area, robust organic framework and hierarchically porous structure, which shows highly catalytic activity in the Friedel-Crafts alkylation of indole with aldehydes and outstanding adsorption efficiency toward cationic dyes.

Original language	English
Pages (from-to)	245-250
Number of pages	6
Journal	Microporous and Mesoporous Materials
Volume	274
DOIs	https://doi.org/10.1016/j.micromeso.2018.08.005
State	Published - 15 Jan 2019

Keywords

Adsorption
Carboxyl group
Diblock copolymers
Friedel-crafts alkylation
Hollow microporous organic nanospheres
Hyper-crosslinking

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10.1016/j.micromeso.2018.08.005

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title = "Carboxyl group functionalized hollow microporous organic nanospheres for efficient catalysis and adsorption",

abstract = "Carboxyl group functionalized hollow microporous organic nanospheres (HMONs-COOH) were successfully synthesized by hyper-crosslinking reaction between polylactide-b-polystyrene (PLA-b-PS) diblock copolymers and 2,4,6-tris(bromomethyl)mesitylene as well as subsequent alkaline KMnO4 oxidation. The synthesized HMONs-COOH possess the high special surface area, robust organic framework and hierarchically porous structure, which shows highly catalytic activity in the Friedel-Crafts alkylation of indole with aldehydes and outstanding adsorption efficiency toward cationic dyes.",

keywords = "Adsorption, Carboxyl group, Diblock copolymers, Friedel-crafts alkylation, Hollow microporous organic nanospheres, Hyper-crosslinking",

author = "Minghong Zhou and Zidong He and Tianqi Wang and Yang Xu and Wei Yu and Buyin Shi and Kun Huang",

note = "Publisher Copyright: {\textcopyright} 2018",

year = "2019",

month = jan,

day = "15",

doi = "10.1016/j.micromeso.2018.08.005",

language = "英语",

volume = "274",

pages = "245--250",

journal = "Microporous and Mesoporous Materials",

issn = "1387-1811",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Carboxyl group functionalized hollow microporous organic nanospheres for efficient catalysis and adsorption

AU - Zhou, Minghong

AU - He, Zidong

AU - Wang, Tianqi

AU - Xu, Yang

AU - Yu, Wei

AU - Shi, Buyin

AU - Huang, Kun

PY - 2019/1/15

Y1 - 2019/1/15

N2 - Carboxyl group functionalized hollow microporous organic nanospheres (HMONs-COOH) were successfully synthesized by hyper-crosslinking reaction between polylactide-b-polystyrene (PLA-b-PS) diblock copolymers and 2,4,6-tris(bromomethyl)mesitylene as well as subsequent alkaline KMnO4 oxidation. The synthesized HMONs-COOH possess the high special surface area, robust organic framework and hierarchically porous structure, which shows highly catalytic activity in the Friedel-Crafts alkylation of indole with aldehydes and outstanding adsorption efficiency toward cationic dyes.

AB - Carboxyl group functionalized hollow microporous organic nanospheres (HMONs-COOH) were successfully synthesized by hyper-crosslinking reaction between polylactide-b-polystyrene (PLA-b-PS) diblock copolymers and 2,4,6-tris(bromomethyl)mesitylene as well as subsequent alkaline KMnO4 oxidation. The synthesized HMONs-COOH possess the high special surface area, robust organic framework and hierarchically porous structure, which shows highly catalytic activity in the Friedel-Crafts alkylation of indole with aldehydes and outstanding adsorption efficiency toward cationic dyes.

KW - Adsorption

KW - Carboxyl group

KW - Diblock copolymers

KW - Friedel-crafts alkylation

KW - Hollow microporous organic nanospheres

KW - Hyper-crosslinking

UR - https://www.scopus.com/pages/publications/85051262473

U2 - 10.1016/j.micromeso.2018.08.005

DO - 10.1016/j.micromeso.2018.08.005

M3 - 文章

AN - SCOPUS:85051262473

SN - 1387-1811

VL - 274

SP - 245

EP - 250

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

ER -

Carboxyl group functionalized hollow microporous organic nanospheres for efficient catalysis and adsorption

Abstract

Keywords

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