Carbon-halogen bond formation by the reductive elimination of PdII species

Xuefeng Jiang; Hui Liu; Zhenhua Gu

doi:10.1002/ajoc.201200035

Carbon-halogen bond formation by the reductive elimination of Pd^II species

Xuefeng Jiang^*
, Hui Liu
, Zhenhua Gu

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University
University of Science and Technology of China

Research output: Contribution to journal › Review article › peer-review

38 Scopus citations

Abstract

It is well known that Pd⁰ undergoes oxidative addition to organic halides, especially aryl or vinyl halides. In the contrast, the formation of organic halides by reductive elimination of RPd^IIX (X=halogen) has been mostly ignored until very recently. This Focus Review discusses recent developments in palladium-catalyzed carbon-halogen bond formation by the reductive elimination of RPd^IIX. These new developments have enriched the scope of palladium-catalyzed reactions, and provide a new way to construct carbon-halogen bonds.

Original language	English
Pages (from-to)	16-24
Number of pages	9
Journal	Asian Journal of Organic Chemistry
Volume	1
Issue number	1
DOIs	https://doi.org/10.1002/ajoc.201200035
State	Published - Sep 2012

Keywords

Alkyl halides
Carbohalogenation
Ligand effect
Palladium
Reductive elimination

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10.1002/ajoc.201200035

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title = "Carbon-halogen bond formation by the reductive elimination of PdII species",

abstract = "It is well known that Pd0 undergoes oxidative addition to organic halides, especially aryl or vinyl halides. In the contrast, the formation of organic halides by reductive elimination of RPdIIX (X=halogen) has been mostly ignored until very recently. This Focus Review discusses recent developments in palladium-catalyzed carbon-halogen bond formation by the reductive elimination of RPdIIX. These new developments have enriched the scope of palladium-catalyzed reactions, and provide a new way to construct carbon-halogen bonds.",

keywords = "Alkyl halides, Carbohalogenation, Ligand effect, Palladium, Reductive elimination",

author = "Xuefeng Jiang and Hui Liu and Zhenhua Gu",

year = "2012",

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doi = "10.1002/ajoc.201200035",

language = "英语",

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T1 - Carbon-halogen bond formation by the reductive elimination of PdII species

AU - Jiang, Xuefeng

AU - Liu, Hui

AU - Gu, Zhenhua

PY - 2012/9

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N2 - It is well known that Pd0 undergoes oxidative addition to organic halides, especially aryl or vinyl halides. In the contrast, the formation of organic halides by reductive elimination of RPdIIX (X=halogen) has been mostly ignored until very recently. This Focus Review discusses recent developments in palladium-catalyzed carbon-halogen bond formation by the reductive elimination of RPdIIX. These new developments have enriched the scope of palladium-catalyzed reactions, and provide a new way to construct carbon-halogen bonds.

AB - It is well known that Pd0 undergoes oxidative addition to organic halides, especially aryl or vinyl halides. In the contrast, the formation of organic halides by reductive elimination of RPdIIX (X=halogen) has been mostly ignored until very recently. This Focus Review discusses recent developments in palladium-catalyzed carbon-halogen bond formation by the reductive elimination of RPdIIX. These new developments have enriched the scope of palladium-catalyzed reactions, and provide a new way to construct carbon-halogen bonds.

KW - Alkyl halides

KW - Carbohalogenation

KW - Ligand effect

KW - Palladium

KW - Reductive elimination

UR - https://www.scopus.com/pages/publications/84879843749

U2 - 10.1002/ajoc.201200035

DO - 10.1002/ajoc.201200035

M3 - 文献综述

AN - SCOPUS:84879843749

SN - 2193-5807

VL - 1

SP - 16

EP - 24

JO - Asian Journal of Organic Chemistry

JF - Asian Journal of Organic Chemistry

IS - 1

ER -

Carbon-halogen bond formation by the reductive elimination of Pd^II species

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Keywords

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