Bottom-up synthesis of monodispersed single-crystalline cyano-bridged coordination polymer nanoflakes

  • Ming Hu
  • , Shinsuke Ishihara
  • , Yusuke Yamauchi*
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

97 Scopus citations

Abstract

A two-dimensional morphology characterizes the nanoflakes that are obtained in the bottom-up synthesis of a single-crystalline coordination polymer, Ni(H2O)2[Ni(CN)4]×x H2O. The 10 nm-thick nanoflakes are well-dispersed in solution and have a very high accessible surface area (240 m2 g-1). Thermal treatment leads to nanoporous NiO with retention of the original flake morphology.

Original languageEnglish
Pages (from-to)1235-1239
Number of pages5
JournalAngewandte Chemie - International Edition
Volume52
Issue number4
DOIs
StatePublished - 21 Jan 2013
Externally publishedYes

Keywords

  • coordination polymers
  • cyano bridges
  • nanoporous materials
  • nickel oxide

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