Bifunctional ligands in combination with phosphines and Lewis acidic phospheniums for the carbonylative Sonogashira reaction

Chen Tan; Peng Wang; Huan Liu; Xiao Li Zhao; Yong Lu; Ye Liu

doi:10.1039/c5cc03697f

Bifunctional ligands in combination with phosphines and Lewis acidic phospheniums for the carbonylative Sonogashira reaction

Chen Tan
, Peng Wang
, Huan Liu
, Xiao Li Zhao
, Yong Lu
, Ye Liu^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

The combination of phosphine-ligated Pd catalysis and phosphenium(v) Lewis acid catalysis has been developed for the carbonylative Sonogashira reaction using phosphino-phosphenium salts (L1-L4) as bifunctional ligands, in which the Lewis acidic phosphenium(v) cations can form secondary bonds with O atoms (in CO) to cooperatively stabilize Pd-acyl intermediates.

Original language	English
Pages (from-to)	10871-10874
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	54
DOIs	https://doi.org/10.1039/c5cc03697f
State	Published - 11 Jul 2015

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title = "Bifunctional ligands in combination with phosphines and Lewis acidic phospheniums for the carbonylative Sonogashira reaction",

abstract = "The combination of phosphine-ligated Pd catalysis and phosphenium(v) Lewis acid catalysis has been developed for the carbonylative Sonogashira reaction using phosphino-phosphenium salts (L1-L4) as bifunctional ligands, in which the Lewis acidic phosphenium(v) cations can form secondary bonds with O atoms (in CO) to cooperatively stabilize Pd-acyl intermediates.",

author = "Chen Tan and Peng Wang and Huan Liu and Zhao, \{Xiao Li\} and Yong Lu and Ye Liu",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

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doi = "10.1039/c5cc03697f",

language = "英语",

volume = "51",

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journal = "Chemical Communications",

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T1 - Bifunctional ligands in combination with phosphines and Lewis acidic phospheniums for the carbonylative Sonogashira reaction

AU - Tan, Chen

AU - Wang, Peng

AU - Liu, Huan

AU - Zhao, Xiao Li

AU - Lu, Yong

AU - Liu, Ye

PY - 2015/7/11

Y1 - 2015/7/11

N2 - The combination of phosphine-ligated Pd catalysis and phosphenium(v) Lewis acid catalysis has been developed for the carbonylative Sonogashira reaction using phosphino-phosphenium salts (L1-L4) as bifunctional ligands, in which the Lewis acidic phosphenium(v) cations can form secondary bonds with O atoms (in CO) to cooperatively stabilize Pd-acyl intermediates.

AB - The combination of phosphine-ligated Pd catalysis and phosphenium(v) Lewis acid catalysis has been developed for the carbonylative Sonogashira reaction using phosphino-phosphenium salts (L1-L4) as bifunctional ligands, in which the Lewis acidic phosphenium(v) cations can form secondary bonds with O atoms (in CO) to cooperatively stabilize Pd-acyl intermediates.

UR - https://www.scopus.com/pages/publications/84935036215

U2 - 10.1039/c5cc03697f

DO - 10.1039/c5cc03697f

M3 - 文章

AN - SCOPUS:84935036215

SN - 1359-7345

VL - 51

SP - 10871

EP - 10874

JO - Chemical Communications

JF - Chemical Communications

IS - 54

ER -

Bifunctional ligands in combination with phosphines and Lewis acidic phospheniums for the carbonylative Sonogashira reaction

Abstract

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