Bicontinuous zeolitic imidazolate framework zif-8@go membrane with enhanced hydrogen selectivity

Aisheng Huang; Qian Liu; Nanyi Wang; Yaqiong Zhu; Jürgen Caro

doi:10.1021/ja5083602

Bicontinuous zeolitic imidazolate framework zif-8@go membrane with enhanced hydrogen selectivity

Aisheng Huang^*
, Qian Liu
, Nanyi Wang
, Yaqiong Zhu
, Jürgen Caro

^*Corresponding author for this work

CAS - Ningbo Institute of Material Technology and Engineering
Leibniz University Hannover

Research output: Contribution to journal › Article › peer-review

330 Scopus citations

Abstract

Through layer-by-layer (LBL) deposition of a graphene oxide (GO) suspension on a semicontinuous ZIF-8 layer, we have developed a novel bicontinuous ZIF-8@GO membrane. Since only the gaps between the ZIF-8 crystals are sealed by the GO layer due to capillary forces and covalent bonds, the gas molecules can only permeate through the ZIF-8 micropore system (0.34 nm). Therefore, the ZIF-8@GO membranes show high hydrogen selectivity. At 250 °C and 1 bar, the mixture separation factors of H₂/CO₂, H₂/N₂, H₂/CH₄, and H₂/C₃H₈ are 14.9, 90.5, 139.1, and 3816.6, with H₂ permeances of about 1.3 × 10^-7 mol·m^-2·s^-1·Pa^-1, which is promising for hydrogen separation and purification by molecular sieving.

Original language	English
Pages (from-to)	14686-14689
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	136
Issue number	42
DOIs	https://doi.org/10.1021/ja5083602
State	Published - 1 Nov 2014
Externally published	Yes

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@article{42d961f4ceb34e0d93cec824a0a892cc,

title = "Bicontinuous zeolitic imidazolate framework zif-8@go membrane with enhanced hydrogen selectivity",

abstract = "Through layer-by-layer (LBL) deposition of a graphene oxide (GO) suspension on a semicontinuous ZIF-8 layer, we have developed a novel bicontinuous ZIF-8@GO membrane. Since only the gaps between the ZIF-8 crystals are sealed by the GO layer due to capillary forces and covalent bonds, the gas molecules can only permeate through the ZIF-8 micropore system (0.34 nm). Therefore, the ZIF-8@GO membranes show high hydrogen selectivity. At 250 °C and 1 bar, the mixture separation factors of H2/CO2, H2/N2, H2/CH4, and H2/C3H8 are 14.9, 90.5, 139.1, and 3816.6, with H2 permeances of about 1.3 × 10-7 mol·m-2·s-1·Pa-1, which is promising for hydrogen separation and purification by molecular sieving.",

author = "Aisheng Huang and Qian Liu and Nanyi Wang and Yaqiong Zhu and J{\"u}rgen Caro",

note = "Publisher Copyright: {\textcopyright} 2014 American Chemical Society.",

year = "2014",

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day = "1",

doi = "10.1021/ja5083602",

language = "英语",

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}

TY - JOUR

T1 - Bicontinuous zeolitic imidazolate framework zif-8@go membrane with enhanced hydrogen selectivity

AU - Huang, Aisheng

AU - Liu, Qian

AU - Wang, Nanyi

AU - Zhu, Yaqiong

AU - Caro, Jürgen

PY - 2014/11/1

Y1 - 2014/11/1

N2 - Through layer-by-layer (LBL) deposition of a graphene oxide (GO) suspension on a semicontinuous ZIF-8 layer, we have developed a novel bicontinuous ZIF-8@GO membrane. Since only the gaps between the ZIF-8 crystals are sealed by the GO layer due to capillary forces and covalent bonds, the gas molecules can only permeate through the ZIF-8 micropore system (0.34 nm). Therefore, the ZIF-8@GO membranes show high hydrogen selectivity. At 250 °C and 1 bar, the mixture separation factors of H2/CO2, H2/N2, H2/CH4, and H2/C3H8 are 14.9, 90.5, 139.1, and 3816.6, with H2 permeances of about 1.3 × 10-7 mol·m-2·s-1·Pa-1, which is promising for hydrogen separation and purification by molecular sieving.

AB - Through layer-by-layer (LBL) deposition of a graphene oxide (GO) suspension on a semicontinuous ZIF-8 layer, we have developed a novel bicontinuous ZIF-8@GO membrane. Since only the gaps between the ZIF-8 crystals are sealed by the GO layer due to capillary forces and covalent bonds, the gas molecules can only permeate through the ZIF-8 micropore system (0.34 nm). Therefore, the ZIF-8@GO membranes show high hydrogen selectivity. At 250 °C and 1 bar, the mixture separation factors of H2/CO2, H2/N2, H2/CH4, and H2/C3H8 are 14.9, 90.5, 139.1, and 3816.6, with H2 permeances of about 1.3 × 10-7 mol·m-2·s-1·Pa-1, which is promising for hydrogen separation and purification by molecular sieving.

UR - https://www.scopus.com/pages/publications/84908406358

U2 - 10.1021/ja5083602

DO - 10.1021/ja5083602

M3 - 文章

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SP - 14686

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 42

ER -

Bicontinuous zeolitic imidazolate framework zif-8@go membrane with enhanced hydrogen selectivity

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