Aromatic Amide Polymers that Form Two Helical Conformations with Twist Sense Bias in Water

Peng Zhang; Zekun Wang; Liang Zhang; Hui Wang; Danwei Zhang; Junli Hou; Zhanting Li

doi:10.1002/cjoc.201600140

Aromatic Amide Polymers that Form Two Helical Conformations with Twist Sense Bias in Water

Peng Zhang, Zekun Wang, Liang Zhang, Hui Wang^*, Danwei Zhang, Junli Hou, Zhanting Li

^*Corresponding author for this work

Fudan University

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Two benzene/2,2′-bipyridine-alternately incorporated amide polymers have been prepared, which are driven by hydrophobicity to form two different helical conformations. Both helices exhibit twist sense bias in water induced by chiral valine side chains and the coordination of the 2,2′-bipyridine unit to the Ni²⁺ions.

Original language	English
Pages (from-to)	678-682
Number of pages	5
Journal	Chinese Journal of Chemistry
Volume	34
Issue number	7
DOIs	https://doi.org/10.1002/cjoc.201600140
State	Published - Jul 2016
Externally published	Yes

Keywords

aromatic amide
foldamer
helix
polymer
twist sense bias

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10.1002/cjoc.201600140

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title = "Aromatic Amide Polymers that Form Two Helical Conformations with Twist Sense Bias in Water",

abstract = "Two benzene/2,2′-bipyridine-alternately incorporated amide polymers have been prepared, which are driven by hydrophobicity to form two different helical conformations. Both helices exhibit twist sense bias in water induced by chiral valine side chains and the coordination of the 2,2′-bipyridine unit to the Ni2+ions.",

keywords = "aromatic amide, foldamer, helix, polymer, twist sense bias",

author = "Peng Zhang and Zekun Wang and Liang Zhang and Hui Wang and Danwei Zhang and Junli Hou and Zhanting Li",

note = "Publisher Copyright: Copyright {\textcopyright} 2016 SIOC, CAS, Shanghai \& WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2016",

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T1 - Aromatic Amide Polymers that Form Two Helical Conformations with Twist Sense Bias in Water

AU - Zhang, Peng

AU - Wang, Zekun

AU - Zhang, Liang

AU - Wang, Hui

AU - Zhang, Danwei

AU - Hou, Junli

AU - Li, Zhanting

PY - 2016/7

Y1 - 2016/7

N2 - Two benzene/2,2′-bipyridine-alternately incorporated amide polymers have been prepared, which are driven by hydrophobicity to form two different helical conformations. Both helices exhibit twist sense bias in water induced by chiral valine side chains and the coordination of the 2,2′-bipyridine unit to the Ni2+ions.

AB - Two benzene/2,2′-bipyridine-alternately incorporated amide polymers have been prepared, which are driven by hydrophobicity to form two different helical conformations. Both helices exhibit twist sense bias in water induced by chiral valine side chains and the coordination of the 2,2′-bipyridine unit to the Ni2+ions.

KW - aromatic amide

KW - foldamer

KW - helix

KW - polymer

KW - twist sense bias

UR - https://www.scopus.com/pages/publications/84964465665

U2 - 10.1002/cjoc.201600140

DO - 10.1002/cjoc.201600140

M3 - 文章

AN - SCOPUS:84964465665

SN - 1001-604X

VL - 34

SP - 678

EP - 682

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 7

ER -

Aromatic Amide Polymers that Form Two Helical Conformations with Twist Sense Bias in Water

Abstract

Keywords

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