Argutalactone, an unprecedented sesquiterpenoid lactone with a 6/5/7 tricyclic system from Incarvillea arguta

Jian Jun Fu; Li Yan Wang; Hong Lin Li; Jiang Jiang Qin; Yun Heng Shen; Jia Gao Cheng; Hui Zi Jin; Wei Dong Zhang

doi:10.1080/10286020.2012.668535

Argutalactone, an unprecedented sesquiterpenoid lactone with a 6/5/7 tricyclic system from Incarvillea arguta

Jian Jun Fu, Li Yan Wang, Hong Lin Li, Jiang Jiang Qin, Yun Heng Shen, Jia Gao Cheng, Hui Zi Jin^*, Wei Dong Zhang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Argutalactone (1), a novel sesquiterpenoid lactone featuring an unprecedented 6/5/7 rigid skeleton, was isolated from the roots of Incarvillea arguta. The structure and relative configuration of 1 were established by extensive analysis of spectroscopic data. The absolute configuration of 1 was determined as 2R,5S,10R,12S based on the analysis of biogenetical transformation, comparison of the optical rotation with literature data, and comparison of the experimental circular dichroism spectrum with the calculated electronic circular dichroism spectra.

Original language	English
Pages (from-to)	496-502
Number of pages	7
Journal	Journal of Asian Natural Products Research
Volume	14
Issue number	5
DOIs	https://doi.org/10.1080/10286020.2012.668535
State	Published - 1 May 2012
Externally published	Yes

Keywords

Incarvillea arguta
argutalactone
density functional calculations
sesquiterpenoid lactone

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10.1080/10286020.2012.668535

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title = "Argutalactone, an unprecedented sesquiterpenoid lactone with a 6/5/7 tricyclic system from Incarvillea arguta",

abstract = "Argutalactone (1), a novel sesquiterpenoid lactone featuring an unprecedented 6/5/7 rigid skeleton, was isolated from the roots of Incarvillea arguta. The structure and relative configuration of 1 were established by extensive analysis of spectroscopic data. The absolute configuration of 1 was determined as 2R,5S,10R,12S based on the analysis of biogenetical transformation, comparison of the optical rotation with literature data, and comparison of the experimental circular dichroism spectrum with the calculated electronic circular dichroism spectra.",

keywords = "Incarvillea arguta, argutalactone, density functional calculations, sesquiterpenoid lactone",

author = "Fu, \{Jian Jun\} and Wang, \{Li Yan\} and Li, \{Hong Lin\} and Qin, \{Jiang Jiang\} and Shen, \{Yun Heng\} and Cheng, \{Jia Gao\} and Jin, \{Hui Zi\} and Zhang, \{Wei Dong\}",

year = "2012",

month = may,

day = "1",

doi = "10.1080/10286020.2012.668535",

language = "英语",

volume = "14",

pages = "496--502",

journal = "Journal of Asian Natural Products Research",

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T1 - Argutalactone, an unprecedented sesquiterpenoid lactone with a 6/5/7 tricyclic system from Incarvillea arguta

AU - Fu, Jian Jun

AU - Wang, Li Yan

AU - Li, Hong Lin

AU - Qin, Jiang Jiang

AU - Shen, Yun Heng

AU - Cheng, Jia Gao

AU - Jin, Hui Zi

AU - Zhang, Wei Dong

PY - 2012/5/1

Y1 - 2012/5/1

N2 - Argutalactone (1), a novel sesquiterpenoid lactone featuring an unprecedented 6/5/7 rigid skeleton, was isolated from the roots of Incarvillea arguta. The structure and relative configuration of 1 were established by extensive analysis of spectroscopic data. The absolute configuration of 1 was determined as 2R,5S,10R,12S based on the analysis of biogenetical transformation, comparison of the optical rotation with literature data, and comparison of the experimental circular dichroism spectrum with the calculated electronic circular dichroism spectra.

AB - Argutalactone (1), a novel sesquiterpenoid lactone featuring an unprecedented 6/5/7 rigid skeleton, was isolated from the roots of Incarvillea arguta. The structure and relative configuration of 1 were established by extensive analysis of spectroscopic data. The absolute configuration of 1 was determined as 2R,5S,10R,12S based on the analysis of biogenetical transformation, comparison of the optical rotation with literature data, and comparison of the experimental circular dichroism spectrum with the calculated electronic circular dichroism spectra.

KW - Incarvillea arguta

KW - argutalactone

KW - density functional calculations

KW - sesquiterpenoid lactone

UR - https://www.scopus.com/pages/publications/84860517782

U2 - 10.1080/10286020.2012.668535

DO - 10.1080/10286020.2012.668535

M3 - 文章

C2 - 22423972

AN - SCOPUS:84860517782

SN - 1028-6020

VL - 14

SP - 496

EP - 502

JO - Journal of Asian Natural Products Research

JF - Journal of Asian Natural Products Research

IS - 5

ER -

Argutalactone, an unprecedented sesquiterpenoid lactone with a 6/5/7 tricyclic system from Incarvillea arguta

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Keywords

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