Application of chiral N-tert-butylsulfinyl vinyl aziridines in Rh(i) catalyzed 1,4-addition of aryl boronic acids to cyclic enones

Qian Chen; Chao Chen; Fang Guo; Wujiong Xia

doi:10.1039/c3cc42673d

Application of chiral N-tert-butylsulfinyl vinyl aziridines in Rh(i) catalyzed 1,4-addition of aryl boronic acids to cyclic enones

Qian Chen, Chao Chen, Fang Guo, Wujiong Xia

Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Chiral N-tert-butylsulfinyl vinyl aziridine ligands prepared from a readily available (R)-tert-butanesulfinamide have been applied in the rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to cyclic enones, which gives high yields and excellent enantioselectivities.

Original language	English
Pages (from-to)	6433-6435
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	57
DOIs	https://doi.org/10.1039/c3cc42673d
State	Published - 20 Jun 2013
Externally published	Yes

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abstract = "Chiral N-tert-butylsulfinyl vinyl aziridine ligands prepared from a readily available (R)-tert-butanesulfinamide have been applied in the rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to cyclic enones, which gives high yields and excellent enantioselectivities.",

author = "Qian Chen and Chao Chen and Fang Guo and Wujiong Xia",

year = "2013",

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doi = "10.1039/c3cc42673d",

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T1 - Application of chiral N-tert-butylsulfinyl vinyl aziridines in Rh(i) catalyzed 1,4-addition of aryl boronic acids to cyclic enones

AU - Chen, Qian

AU - Chen, Chao

AU - Guo, Fang

AU - Xia, Wujiong

PY - 2013/6/20

Y1 - 2013/6/20

N2 - Chiral N-tert-butylsulfinyl vinyl aziridine ligands prepared from a readily available (R)-tert-butanesulfinamide have been applied in the rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to cyclic enones, which gives high yields and excellent enantioselectivities.

AB - Chiral N-tert-butylsulfinyl vinyl aziridine ligands prepared from a readily available (R)-tert-butanesulfinamide have been applied in the rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to cyclic enones, which gives high yields and excellent enantioselectivities.

UR - https://www.scopus.com/pages/publications/84880893374

U2 - 10.1039/c3cc42673d

DO - 10.1039/c3cc42673d

M3 - 文章

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AN - SCOPUS:84880893374

SN - 1359-7345

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JO - Chemical Communications

JF - Chemical Communications

IS - 57

ER -

Application of chiral N-tert-butylsulfinyl vinyl aziridines in Rh(i) catalyzed 1,4-addition of aryl boronic acids to cyclic enones

Abstract

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