Anthracene-Functionalized Metallacage with Fluorescence Response Behavior to Anions

Zhi Yong Zeng; Xiaoli Zhao; Junhai Huang; Jing Zhu; Tongxia Jin; Lianrui Hu; Wei Tao Dou; Lin Xu

doi:10.1055/s-0042-1751486

Anthracene-Functionalized Metallacage with Fluorescence Response Behavior to Anions

Zhi Yong Zeng
, Xiaoli Zhao
, Junhai Huang^*
, Jing Zhu
, Tongxia Jin
, Lianrui Hu
, Wei Tao Dou
, Lin Xu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Functionalized metallacages have attracted tremendous attention in recent years due to their potential applications in optical sensing, catalysis, and recognition. A novel anthracene-functionalized metallacage was synthesized and characterized in detail by UV/vis spectroscopy, 1D/2D NMR, electrospray ionization time-of-flight mass spectrometry, and X-ray single crystal diffraction. This metallacage exhibited a specific fluorescence enhancement response to OH , PO₄³, and AcO^-anions, and further analysis indicated that this was due to anioninduced metallacage disassembly.

Original language	English
Pages (from-to)	130-134
Number of pages	5
Journal	Synlett
Volume	35
Issue number	1
DOIs	https://doi.org/10.1055/s-0042-1751486
State	Published - 9 May 2023

Keywords

anion recognition
fluorescence
metallacages
self-assembly
supramolecular chemistry

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title = "Anthracene-Functionalized Metallacage with Fluorescence Response Behavior to Anions",

abstract = "Functionalized metallacages have attracted tremendous attention in recent years due to their potential applications in optical sensing, catalysis, and recognition. A novel anthracene-functionalized metallacage was synthesized and characterized in detail by UV/vis spectroscopy, 1D/2D NMR, electrospray ionization time-of-flight mass spectrometry, and X-ray single crystal diffraction. This metallacage exhibited a specific fluorescence enhancement response to OH , PO43, and AcO-anions, and further analysis indicated that this was due to anioninduced metallacage disassembly.",

keywords = "anion recognition, fluorescence, metallacages, self-assembly, supramolecular chemistry",

author = "Zeng, \{Zhi Yong\} and Xiaoli Zhao and Junhai Huang and Jing Zhu and Tongxia Jin and Lianrui Hu and Dou, \{Wei Tao\} and Lin Xu",

year = "2023",

month = may,

day = "9",

doi = "10.1055/s-0042-1751486",

language = "英语",

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}

TY - JOUR

T1 - Anthracene-Functionalized Metallacage with Fluorescence Response Behavior to Anions

AU - Zeng, Zhi Yong

AU - Zhao, Xiaoli

AU - Huang, Junhai

AU - Zhu, Jing

AU - Jin, Tongxia

AU - Hu, Lianrui

AU - Dou, Wei Tao

AU - Xu, Lin

PY - 2023/5/9

Y1 - 2023/5/9

N2 - Functionalized metallacages have attracted tremendous attention in recent years due to their potential applications in optical sensing, catalysis, and recognition. A novel anthracene-functionalized metallacage was synthesized and characterized in detail by UV/vis spectroscopy, 1D/2D NMR, electrospray ionization time-of-flight mass spectrometry, and X-ray single crystal diffraction. This metallacage exhibited a specific fluorescence enhancement response to OH , PO43, and AcO-anions, and further analysis indicated that this was due to anioninduced metallacage disassembly.

AB - Functionalized metallacages have attracted tremendous attention in recent years due to their potential applications in optical sensing, catalysis, and recognition. A novel anthracene-functionalized metallacage was synthesized and characterized in detail by UV/vis spectroscopy, 1D/2D NMR, electrospray ionization time-of-flight mass spectrometry, and X-ray single crystal diffraction. This metallacage exhibited a specific fluorescence enhancement response to OH , PO43, and AcO-anions, and further analysis indicated that this was due to anioninduced metallacage disassembly.

KW - anion recognition

KW - fluorescence

KW - metallacages

KW - self-assembly

KW - supramolecular chemistry

UR - https://www.scopus.com/pages/publications/85172275903

U2 - 10.1055/s-0042-1751486

DO - 10.1055/s-0042-1751486

M3 - 文章

AN - SCOPUS:85172275903

SN - 0936-5214

VL - 35

SP - 130

EP - 134

JO - Synlett

JF - Synlett

IS - 1

ER -

Anthracene-Functionalized Metallacage with Fluorescence Response Behavior to Anions

Abstract

Keywords

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