Anion recognition by a novel Fipronil-based receptor: efficient deprotonation or stable intermolecular hydrogen bonding

Chuanxiang Liu; Xuhong Qian; Jiaobing Wang; Zhong Li

doi:10.1016/j.tetlet.2007.10.155

Anion recognition by a novel Fipronil-based receptor: efficient deprotonation or stable intermolecular hydrogen bonding

Chuanxiang Liu
, Xuhong Qian^*
, Jiaobing Wang
, Zhong Li

^*Corresponding author for this work

East China University of Science and Technology

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Strong electron-deficient heterocycles of acetyl Fipronil (F3) was designed and synthesized, its ability for anion recognition was investigated by UV and NMR analyses. This novel Fipronil-based receptor F3 shows strong binding affinity with acetate (≥10⁷ M^-1), phosphate or fluoride ion through efficient deprotonation. In addition, its interaction with chloride anion or other weak base anions through stable intermolecular H-bonding was also reported.

Original language	English
Pages (from-to)	1087-1090
Number of pages	4
Journal	Tetrahedron Letters
Volume	49
Issue number	6
DOIs	https://doi.org/10.1016/j.tetlet.2007.10.155
State	Published - 4 Feb 2008
Externally published	Yes

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10.1016/j.tetlet.2007.10.155

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title = "Anion recognition by a novel Fipronil-based receptor: efficient deprotonation or stable intermolecular hydrogen bonding",

abstract = "Strong electron-deficient heterocycles of acetyl Fipronil (F3) was designed and synthesized, its ability for anion recognition was investigated by UV and NMR analyses. This novel Fipronil-based receptor F3 shows strong binding affinity with acetate (≥107 M-1), phosphate or fluoride ion through efficient deprotonation. In addition, its interaction with chloride anion or other weak base anions through stable intermolecular H-bonding was also reported.",

author = "Chuanxiang Liu and Xuhong Qian and Jiaobing Wang and Zhong Li",

year = "2008",

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T1 - Anion recognition by a novel Fipronil-based receptor

T2 - efficient deprotonation or stable intermolecular hydrogen bonding

AU - Liu, Chuanxiang

AU - Qian, Xuhong

AU - Wang, Jiaobing

AU - Li, Zhong

PY - 2008/2/4

Y1 - 2008/2/4

N2 - Strong electron-deficient heterocycles of acetyl Fipronil (F3) was designed and synthesized, its ability for anion recognition was investigated by UV and NMR analyses. This novel Fipronil-based receptor F3 shows strong binding affinity with acetate (≥107 M-1), phosphate or fluoride ion through efficient deprotonation. In addition, its interaction with chloride anion or other weak base anions through stable intermolecular H-bonding was also reported.

AB - Strong electron-deficient heterocycles of acetyl Fipronil (F3) was designed and synthesized, its ability for anion recognition was investigated by UV and NMR analyses. This novel Fipronil-based receptor F3 shows strong binding affinity with acetate (≥107 M-1), phosphate or fluoride ion through efficient deprotonation. In addition, its interaction with chloride anion or other weak base anions through stable intermolecular H-bonding was also reported.

UR - https://www.scopus.com/pages/publications/37849035903

U2 - 10.1016/j.tetlet.2007.10.155

DO - 10.1016/j.tetlet.2007.10.155

M3 - 文章

AN - SCOPUS:37849035903

SN - 0040-4039

VL - 49

SP - 1087

EP - 1090

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 6

ER -

Anion recognition by a novel Fipronil-based receptor: efficient deprotonation or stable intermolecular hydrogen bonding

Abstract

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