An unexpected in situ formation of a substitute tetrazole ligand and its Mn(II) and Cu(II) complexes

Xiao Jie Mo; En Qing Gao; Zheng He; Wen Jun Li; Chun Hua Yan

doi:10.1016/j.inoche.2003.12.013

An unexpected in situ formation of a substitute tetrazole ligand and its Mn(II) and Cu(II) complexes

Xiao Jie Mo
, En Qing Gao
, Zheng He
, Wen Jun Li
, Chun Hua Yan^*

^*Corresponding author for this work

Peking University
University of Science and Technology Beijing

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

The reaction of 2-aminomethylpyridine, benzaldehyde and NaN₃ in the presence of the metal ions leads to an unexpected in situ formation of a substituted tetrazole, 5-(2-pyridyl)-1H-tetrazole, and its Mn(II) and Cu(II) compounds MnL₂(H₂O)₂ (1) and CuL ₂(H₂O)₂ (2). In these structures, mononuclear units connect each other via hydrogen bonds to form a two-dimensional network.

Original language	English
Pages (from-to)	353-355
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	7
Issue number	3
DOIs	https://doi.org/10.1016/j.inoche.2003.12.013
State	Published - Mar 2004
Externally published	Yes

Keywords

Azide
Hydrogen bond
In situ formation
Tetrazole

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10.1016/j.inoche.2003.12.013

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title = "An unexpected in situ formation of a substitute tetrazole ligand and its Mn(II) and Cu(II) complexes",

abstract = "The reaction of 2-aminomethylpyridine, benzaldehyde and NaN3 in the presence of the metal ions leads to an unexpected in situ formation of a substituted tetrazole, 5-(2-pyridyl)-1H-tetrazole, and its Mn(II) and Cu(II) compounds MnL2(H2O)2 (1) and CuL 2(H2O)2 (2). In these structures, mononuclear units connect each other via hydrogen bonds to form a two-dimensional network.",

keywords = "Azide, Hydrogen bond, In situ formation, Tetrazole",

author = "Mo, \{Xiao Jie\} and Gao, \{En Qing\} and Zheng He and Li, \{Wen Jun\} and Yan, \{Chun Hua\}",

year = "2004",

month = mar,

doi = "10.1016/j.inoche.2003.12.013",

language = "英语",

volume = "7",

pages = "353--355",

journal = "Inorganic Chemistry Communications",

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}

TY - JOUR

T1 - An unexpected in situ formation of a substitute tetrazole ligand and its Mn(II) and Cu(II) complexes

AU - Mo, Xiao Jie

AU - Gao, En Qing

AU - He, Zheng

AU - Li, Wen Jun

AU - Yan, Chun Hua

PY - 2004/3

Y1 - 2004/3

N2 - The reaction of 2-aminomethylpyridine, benzaldehyde and NaN3 in the presence of the metal ions leads to an unexpected in situ formation of a substituted tetrazole, 5-(2-pyridyl)-1H-tetrazole, and its Mn(II) and Cu(II) compounds MnL2(H2O)2 (1) and CuL 2(H2O)2 (2). In these structures, mononuclear units connect each other via hydrogen bonds to form a two-dimensional network.

AB - The reaction of 2-aminomethylpyridine, benzaldehyde and NaN3 in the presence of the metal ions leads to an unexpected in situ formation of a substituted tetrazole, 5-(2-pyridyl)-1H-tetrazole, and its Mn(II) and Cu(II) compounds MnL2(H2O)2 (1) and CuL 2(H2O)2 (2). In these structures, mononuclear units connect each other via hydrogen bonds to form a two-dimensional network.

KW - Azide

KW - Hydrogen bond

KW - In situ formation

KW - Tetrazole

UR - https://www.scopus.com/pages/publications/1242283893

U2 - 10.1016/j.inoche.2003.12.013

DO - 10.1016/j.inoche.2003.12.013

M3 - 文章

AN - SCOPUS:1242283893

SN - 1387-7003

VL - 7

SP - 353

EP - 355

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 3

ER -

An unexpected in situ formation of a substitute tetrazole ligand and its Mn(II) and Cu(II) complexes

Abstract

Keywords

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