An: In situ approach to functionalize metal-organic frameworks with tertiary aliphatic amino groups

Fu Gui Xi; Wei Sun; Zhi Yun Dong; Ning Ning Yang; Teng Gong; En Qing Gao

doi:10.1039/d0cc05568a

An: In situ approach to functionalize metal-organic frameworks with tertiary aliphatic amino groups

Fu Gui Xi^*, Wei Sun, Zhi Yun Dong, Ning Ning Yang, Teng Gong, En Qing Gao^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Metal-catalyzed reductive amination of formyl-containing linkers with N,N-dialkylformamide solvents is concomitant with the solvothermal coordination assembly, leading to novel MOFs functionalized with tertiary aliphatic amino groups. This illustrates a novel one-pot strategy to functionalize MOFs through in situ organic transformation. The UiO-66 MOFs partially functionalized with the amino groups are highly active heterogeneous catalysts for Knoevenagel condensation.

Original language	English
Pages (from-to)	13177-13180
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	86
DOIs	https://doi.org/10.1039/d0cc05568a
State	Published - 7 Nov 2020

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title = "An: In situ approach to functionalize metal-organic frameworks with tertiary aliphatic amino groups",

abstract = "Metal-catalyzed reductive amination of formyl-containing linkers with N,N-dialkylformamide solvents is concomitant with the solvothermal coordination assembly, leading to novel MOFs functionalized with tertiary aliphatic amino groups. This illustrates a novel one-pot strategy to functionalize MOFs through in situ organic transformation. The UiO-66 MOFs partially functionalized with the amino groups are highly active heterogeneous catalysts for Knoevenagel condensation.",

author = "Xi, \{Fu Gui\} and Wei Sun and Dong, \{Zhi Yun\} and Yang, \{Ning Ning\} and Teng Gong and Gao, \{En Qing\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2020",

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doi = "10.1039/d0cc05568a",

language = "英语",

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T2 - In situ approach to functionalize metal-organic frameworks with tertiary aliphatic amino groups

AU - Xi, Fu Gui

AU - Sun, Wei

AU - Dong, Zhi Yun

AU - Yang, Ning Ning

AU - Gong, Teng

AU - Gao, En Qing

PY - 2020/11/7

Y1 - 2020/11/7

N2 - Metal-catalyzed reductive amination of formyl-containing linkers with N,N-dialkylformamide solvents is concomitant with the solvothermal coordination assembly, leading to novel MOFs functionalized with tertiary aliphatic amino groups. This illustrates a novel one-pot strategy to functionalize MOFs through in situ organic transformation. The UiO-66 MOFs partially functionalized with the amino groups are highly active heterogeneous catalysts for Knoevenagel condensation.

AB - Metal-catalyzed reductive amination of formyl-containing linkers with N,N-dialkylformamide solvents is concomitant with the solvothermal coordination assembly, leading to novel MOFs functionalized with tertiary aliphatic amino groups. This illustrates a novel one-pot strategy to functionalize MOFs through in situ organic transformation. The UiO-66 MOFs partially functionalized with the amino groups are highly active heterogeneous catalysts for Knoevenagel condensation.

UR - https://www.scopus.com/pages/publications/85094982560

U2 - 10.1039/d0cc05568a

DO - 10.1039/d0cc05568a

M3 - 文章

C2 - 33020765

AN - SCOPUS:85094982560

SN - 1359-7345

VL - 56

SP - 13177

EP - 13180

JO - Chemical Communications

JF - Chemical Communications

IS - 86

ER -

An: In situ approach to functionalize metal-organic frameworks with tertiary aliphatic amino groups

Abstract

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