An efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H2O as the hydrogen source

Huan Liu; Da Yang; Dong Liang Wang; Peng Wang; Yong Lu; Vo Thanh Giang; Ye Liu

doi:10.1039/c8cc03431a

An efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H₂O as the hydrogen source

Huan Liu, Da Yang, Dong Liang Wang, Peng Wang, Yong Lu, Vo Thanh Giang, Ye Liu

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Hydroaminomethylation of olefins with H₂O as the hydrogen source was accomplished over an Ir-catalyst with the involvement of an ionic diphosphine (L6). The use of H₂O as the hydrogen source could completely inhibit the hydrogenation of olefins. The π-accepting ability and improved stability of L6 endowed the corresponding Ir-catalyst with high activity and good longevity for recycling uses.

Original language	English
Pages (from-to)	7979-7982
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	57
DOIs	https://doi.org/10.1039/c8cc03431a
State	Published - 2018

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title = "An efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H2O as the hydrogen source",

abstract = "Hydroaminomethylation of olefins with H2O as the hydrogen source was accomplished over an Ir-catalyst with the involvement of an ionic diphosphine (L6). The use of H2O as the hydrogen source could completely inhibit the hydrogenation of olefins. The π-accepting ability and improved stability of L6 endowed the corresponding Ir-catalyst with high activity and good longevity for recycling uses.",

author = "Huan Liu and Da Yang and Wang, \{Dong Liang\} and Peng Wang and Yong Lu and Giang, \{Vo Thanh\} and Ye Liu",

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doi = "10.1039/c8cc03431a",

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volume = "54",

pages = "7979--7982",

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T1 - An efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H2O as the hydrogen source

AU - Liu, Huan

AU - Yang, Da

AU - Wang, Dong Liang

AU - Wang, Peng

AU - Lu, Yong

AU - Giang, Vo Thanh

AU - Liu, Ye

PY - 2018

Y1 - 2018

N2 - Hydroaminomethylation of olefins with H2O as the hydrogen source was accomplished over an Ir-catalyst with the involvement of an ionic diphosphine (L6). The use of H2O as the hydrogen source could completely inhibit the hydrogenation of olefins. The π-accepting ability and improved stability of L6 endowed the corresponding Ir-catalyst with high activity and good longevity for recycling uses.

AB - Hydroaminomethylation of olefins with H2O as the hydrogen source was accomplished over an Ir-catalyst with the involvement of an ionic diphosphine (L6). The use of H2O as the hydrogen source could completely inhibit the hydrogenation of olefins. The π-accepting ability and improved stability of L6 endowed the corresponding Ir-catalyst with high activity and good longevity for recycling uses.

UR - https://www.scopus.com/pages/publications/85049834960

U2 - 10.1039/c8cc03431a

DO - 10.1039/c8cc03431a

M3 - 文章

C2 - 29963658

AN - SCOPUS:85049834960

SN - 1359-7345

VL - 54

SP - 7979

EP - 7982

JO - Chemical Communications

JF - Chemical Communications

IS - 57

ER -

An efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H₂O as the hydrogen source

Abstract

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