Amphiphilic Titanosilicates as Pickering Interfacial Catalysts for Liquid-Phase Oxidation Reactions

Yulin Yang; Wen Juan Zhou; Armin Liebens; Jean Marc Clacens; Marc Pera-Titus; Peng Wu

doi:10.1021/acs.jpcc.5b07175

Amphiphilic Titanosilicates as Pickering Interfacial Catalysts for Liquid-Phase Oxidation Reactions

Yulin Yang
, Wen Juan Zhou
, Armin Liebens
, Jean Marc Clacens
, Marc Pera-Titus^*
, Peng Wu

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

Monodispersed amphiphilic zeolite/mesosilica composite material TS-1@KCC-1 (TK), which could stabilize Pickering emulsions for the benzene/H₂O₂ system, has been synthesized, and its physicochemical properties have been investigated in detail. The amphiphilic TK catalyst displayed a higher catalytic activity under Pickering interfacial catalysis (PIC) than under phase-boundary catalysis (PBC) and conventional reaction conditions in the hydroxylation of benzene by hydrogen peroxide without cosolvent and under static conditions. Under optimized conditions, a TS-1@KCC-1 catalyst grafted with octyl chains (2.42 wt %) could afford an interfacial activity of 1.1 mol (Ti-mol)^-1. Moreover, PIC reaction conditions exhibited an excellent thermal stability and good reusability.

Original language	English
Pages (from-to)	25377-25384
Number of pages	8
Journal	Journal of Physical Chemistry C
Volume	119
Issue number	45
DOIs	https://doi.org/10.1021/acs.jpcc.5b07175
State	Published - 12 Nov 2015

Access to Document

10.1021/acs.jpcc.5b07175

Cite this

@article{e35acde7946f48fcb37711303d0f1d61,

title = "Amphiphilic Titanosilicates as Pickering Interfacial Catalysts for Liquid-Phase Oxidation Reactions",

abstract = "Monodispersed amphiphilic zeolite/mesosilica composite material TS-1@KCC-1 (TK), which could stabilize Pickering emulsions for the benzene/H2O2 system, has been synthesized, and its physicochemical properties have been investigated in detail. The amphiphilic TK catalyst displayed a higher catalytic activity under Pickering interfacial catalysis (PIC) than under phase-boundary catalysis (PBC) and conventional reaction conditions in the hydroxylation of benzene by hydrogen peroxide without cosolvent and under static conditions. Under optimized conditions, a TS-1@KCC-1 catalyst grafted with octyl chains (2.42 wt \%) could afford an interfacial activity of 1.1 mol (Ti-mol)-1. Moreover, PIC reaction conditions exhibited an excellent thermal stability and good reusability.",

author = "Yulin Yang and Zhou, \{Wen Juan\} and Armin Liebens and Clacens, \{Jean Marc\} and Marc Pera-Titus and Peng Wu",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = nov,

day = "12",

doi = "10.1021/acs.jpcc.5b07175",

language = "英语",

volume = "119",

pages = "25377--25384",

journal = "Journal of Physical Chemistry C",

issn = "1932-7447",

publisher = "American Chemical Society",

number = "45",

}

TY - JOUR

T1 - Amphiphilic Titanosilicates as Pickering Interfacial Catalysts for Liquid-Phase Oxidation Reactions

AU - Yang, Yulin

AU - Zhou, Wen Juan

AU - Liebens, Armin

AU - Clacens, Jean Marc

AU - Pera-Titus, Marc

AU - Wu, Peng

PY - 2015/11/12

Y1 - 2015/11/12

N2 - Monodispersed amphiphilic zeolite/mesosilica composite material TS-1@KCC-1 (TK), which could stabilize Pickering emulsions for the benzene/H2O2 system, has been synthesized, and its physicochemical properties have been investigated in detail. The amphiphilic TK catalyst displayed a higher catalytic activity under Pickering interfacial catalysis (PIC) than under phase-boundary catalysis (PBC) and conventional reaction conditions in the hydroxylation of benzene by hydrogen peroxide without cosolvent and under static conditions. Under optimized conditions, a TS-1@KCC-1 catalyst grafted with octyl chains (2.42 wt %) could afford an interfacial activity of 1.1 mol (Ti-mol)-1. Moreover, PIC reaction conditions exhibited an excellent thermal stability and good reusability.

AB - Monodispersed amphiphilic zeolite/mesosilica composite material TS-1@KCC-1 (TK), which could stabilize Pickering emulsions for the benzene/H2O2 system, has been synthesized, and its physicochemical properties have been investigated in detail. The amphiphilic TK catalyst displayed a higher catalytic activity under Pickering interfacial catalysis (PIC) than under phase-boundary catalysis (PBC) and conventional reaction conditions in the hydroxylation of benzene by hydrogen peroxide without cosolvent and under static conditions. Under optimized conditions, a TS-1@KCC-1 catalyst grafted with octyl chains (2.42 wt %) could afford an interfacial activity of 1.1 mol (Ti-mol)-1. Moreover, PIC reaction conditions exhibited an excellent thermal stability and good reusability.

UR - https://www.scopus.com/pages/publications/84946962487

U2 - 10.1021/acs.jpcc.5b07175

DO - 10.1021/acs.jpcc.5b07175

M3 - 文章

AN - SCOPUS:84946962487

SN - 1932-7447

VL - 119

SP - 25377

EP - 25384

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

IS - 45

ER -

Amphiphilic Titanosilicates as Pickering Interfacial Catalysts for Liquid-Phase Oxidation Reactions

Abstract

Access to Document

Other files and links

Fingerprint

Cite this