Amphiphilic ABA triblock copolymers via combination of ROMP and ATRP in ionic liquid: Synthesis, characterization, and self-assembly

Meiran Xie; Yi Kong; Huijing Han; Jiaxin Shi; Liang Ding; Chunmei Song; Yiqun Zhang

doi:10.1016/j.reactfunctpolym.2008.09.001

Amphiphilic ABA triblock copolymers via combination of ROMP and ATRP in ionic liquid: Synthesis, characterization, and self-assembly

Meiran Xie^*
, Yi Kong
, Huijing Han
, Jiaxin Shi
, Liang Ding
, Chunmei Song
, Yiqun Zhang

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

A new amphiphilic ABA triblock copolymer was synthesized by ring-opening metathesis polymerization (ROMP) and atom transfer radical polymerization (ATRP) in ionic liquid (IL). The bromo-terminated macroinitiator was prepared via ROMP of norbornene derivative, which is compatible with ionic liquid [bmim][BF₄], in conjunction with a chain transfer agent (CTA) in [bmim][BF₄]. ROMP with CTA in [bmim][BF₄] exhibited a different performance by changing the reaction conditions, and importantly there has been a good control over polymerization process and relatively low polydispersity index of polymer in [bmim][BF₄]. Based on the telechelic macroinitiator, the amphiphilic ABA triblock copolymer was synthesized by ATRP in [bmim][BF₄]. The prepared PDMAEMA-PNBEDE-PDMAEMA triblock copolymer can self-assemble spontaneously in H₂O to form polymeric micelles, which was characterized by DLS, AFM, and TEM.

Original language	English
Pages (from-to)	1601-1608
Number of pages	8
Journal	Reactive and Functional Polymers
Volume	68
Issue number	12
DOIs	https://doi.org/10.1016/j.reactfunctpolym.2008.09.001
State	Published - Dec 2008

Keywords

Atom transfer radical polymerization (ATRP)
Block copolymers
Ionic liquid
Micelles
Ring-opening metathesis polymerization (ROMP)

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10.1016/j.reactfunctpolym.2008.09.001

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title = "Amphiphilic ABA triblock copolymers via combination of ROMP and ATRP in ionic liquid: Synthesis, characterization, and self-assembly",

abstract = "A new amphiphilic ABA triblock copolymer was synthesized by ring-opening metathesis polymerization (ROMP) and atom transfer radical polymerization (ATRP) in ionic liquid (IL). The bromo-terminated macroinitiator was prepared via ROMP of norbornene derivative, which is compatible with ionic liquid [bmim][BF4], in conjunction with a chain transfer agent (CTA) in [bmim][BF4]. ROMP with CTA in [bmim][BF4] exhibited a different performance by changing the reaction conditions, and importantly there has been a good control over polymerization process and relatively low polydispersity index of polymer in [bmim][BF4]. Based on the telechelic macroinitiator, the amphiphilic ABA triblock copolymer was synthesized by ATRP in [bmim][BF4]. The prepared PDMAEMA-PNBEDE-PDMAEMA triblock copolymer can self-assemble spontaneously in H2O to form polymeric micelles, which was characterized by DLS, AFM, and TEM.",

keywords = "Atom transfer radical polymerization (ATRP), Block copolymers, Ionic liquid, Micelles, Ring-opening metathesis polymerization (ROMP)",

author = "Meiran Xie and Yi Kong and Huijing Han and Jiaxin Shi and Liang Ding and Chunmei Song and Yiqun Zhang",

year = "2008",

month = dec,

doi = "10.1016/j.reactfunctpolym.2008.09.001",

language = "英语",

volume = "68",

pages = "1601--1608",

journal = "Reactive and Functional Polymers",

issn = "1381-5148",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Amphiphilic ABA triblock copolymers via combination of ROMP and ATRP in ionic liquid

T2 - Synthesis, characterization, and self-assembly

AU - Xie, Meiran

AU - Kong, Yi

AU - Han, Huijing

AU - Shi, Jiaxin

AU - Ding, Liang

AU - Song, Chunmei

AU - Zhang, Yiqun

PY - 2008/12

Y1 - 2008/12

N2 - A new amphiphilic ABA triblock copolymer was synthesized by ring-opening metathesis polymerization (ROMP) and atom transfer radical polymerization (ATRP) in ionic liquid (IL). The bromo-terminated macroinitiator was prepared via ROMP of norbornene derivative, which is compatible with ionic liquid [bmim][BF4], in conjunction with a chain transfer agent (CTA) in [bmim][BF4]. ROMP with CTA in [bmim][BF4] exhibited a different performance by changing the reaction conditions, and importantly there has been a good control over polymerization process and relatively low polydispersity index of polymer in [bmim][BF4]. Based on the telechelic macroinitiator, the amphiphilic ABA triblock copolymer was synthesized by ATRP in [bmim][BF4]. The prepared PDMAEMA-PNBEDE-PDMAEMA triblock copolymer can self-assemble spontaneously in H2O to form polymeric micelles, which was characterized by DLS, AFM, and TEM.

AB - A new amphiphilic ABA triblock copolymer was synthesized by ring-opening metathesis polymerization (ROMP) and atom transfer radical polymerization (ATRP) in ionic liquid (IL). The bromo-terminated macroinitiator was prepared via ROMP of norbornene derivative, which is compatible with ionic liquid [bmim][BF4], in conjunction with a chain transfer agent (CTA) in [bmim][BF4]. ROMP with CTA in [bmim][BF4] exhibited a different performance by changing the reaction conditions, and importantly there has been a good control over polymerization process and relatively low polydispersity index of polymer in [bmim][BF4]. Based on the telechelic macroinitiator, the amphiphilic ABA triblock copolymer was synthesized by ATRP in [bmim][BF4]. The prepared PDMAEMA-PNBEDE-PDMAEMA triblock copolymer can self-assemble spontaneously in H2O to form polymeric micelles, which was characterized by DLS, AFM, and TEM.

KW - Atom transfer radical polymerization (ATRP)

KW - Block copolymers

KW - Ionic liquid

KW - Micelles

KW - Ring-opening metathesis polymerization (ROMP)

UR - https://www.scopus.com/pages/publications/55949130560

U2 - 10.1016/j.reactfunctpolym.2008.09.001

DO - 10.1016/j.reactfunctpolym.2008.09.001

M3 - 文章

AN - SCOPUS:55949130560

SN - 1381-5148

VL - 68

SP - 1601

EP - 1608

JO - Reactive and Functional Polymers

JF - Reactive and Functional Polymers

IS - 12

ER -

Amphiphilic ABA triblock copolymers via combination of ROMP and ATRP in ionic liquid: Synthesis, characterization, and self-assembly

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Keywords

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