Amino-functionalized hollow microporous organic nanospheres for pd supported catalysis and I2 uptake

Zidong He; Tianqi Wang; Yang Xu; Minghong Zhou; Wei Yu; Buyin Shi; Kun Huang

doi:10.1002/pola.29092

Amino-functionalized hollow microporous organic nanospheres for pd supported catalysis and I₂ uptake

Zidong He
, Tianqi Wang
, Yang Xu
, Minghong Zhou
, Wei Yu
, Buyin Shi
, Kun Huang^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Amino-functionalized hollow microporous organic nanospheres (NH₂-HMONs) were successfully synthesized by a combination of hyper-crosslinking mediated self-assembly process and a post-modification strategy. Benefiting from amino groups and hollow microporous structure, the resultant NH₂-HMONs can be used to immobilize Pd nanoparticles (Pd@NH₂-HMONs) and enhance the adsorption capacity for iodine. The obtained Pd@NH₂-HMONs exhibited outstanding catalytic activity for hydrogenation of nitroarenes to aniline analogues. This strategy represents a new method for the preparation of porous organic polymers with special morphologies and functionalizations for potential applications including adsorption, separation, and catalysis.

Original language	English
Pages (from-to)	2045-2052
Number of pages	8
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	56
Issue number	18
DOIs	https://doi.org/10.1002/pola.29092
State	Published - 15 Sep 2018

Keywords

I uptake
amino-functionalization
hollow microporous organic nanospheres
supported Pd nanoparticles

Access to Document

10.1002/pola.29092

Cite this

@article{472ef5ecab694d57b7ebb7781d1ac4a8,

title = "Amino-functionalized hollow microporous organic nanospheres for pd supported catalysis and I2 uptake",

abstract = "Amino-functionalized hollow microporous organic nanospheres (NH2-HMONs) were successfully synthesized by a combination of hyper-crosslinking mediated self-assembly process and a post-modification strategy. Benefiting from amino groups and hollow microporous structure, the resultant NH2-HMONs can be used to immobilize Pd nanoparticles (Pd@NH2-HMONs) and enhance the adsorption capacity for iodine. The obtained Pd@NH2-HMONs exhibited outstanding catalytic activity for hydrogenation of nitroarenes to aniline analogues. This strategy represents a new method for the preparation of porous organic polymers with special morphologies and functionalizations for potential applications including adsorption, separation, and catalysis.",

keywords = "I uptake, amino-functionalization, hollow microporous organic nanospheres, supported Pd nanoparticles",

author = "Zidong He and Tianqi Wang and Yang Xu and Minghong Zhou and Wei Yu and Buyin Shi and Kun Huang",

note = "Publisher Copyright: {\textcopyright} 2018 Wiley Periodicals, Inc.",

year = "2018",

month = sep,

day = "15",

doi = "10.1002/pola.29092",

language = "英语",

volume = "56",

pages = "2045--2052",

journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

issn = "0887-624X",

publisher = "John Wiley \& Sons Inc.",

number = "18",

}

TY - JOUR

T1 - Amino-functionalized hollow microporous organic nanospheres for pd supported catalysis and I2 uptake

AU - He, Zidong

AU - Wang, Tianqi

AU - Xu, Yang

AU - Zhou, Minghong

AU - Yu, Wei

AU - Shi, Buyin

AU - Huang, Kun

PY - 2018/9/15

Y1 - 2018/9/15

N2 - Amino-functionalized hollow microporous organic nanospheres (NH2-HMONs) were successfully synthesized by a combination of hyper-crosslinking mediated self-assembly process and a post-modification strategy. Benefiting from amino groups and hollow microporous structure, the resultant NH2-HMONs can be used to immobilize Pd nanoparticles (Pd@NH2-HMONs) and enhance the adsorption capacity for iodine. The obtained Pd@NH2-HMONs exhibited outstanding catalytic activity for hydrogenation of nitroarenes to aniline analogues. This strategy represents a new method for the preparation of porous organic polymers with special morphologies and functionalizations for potential applications including adsorption, separation, and catalysis.

AB - Amino-functionalized hollow microporous organic nanospheres (NH2-HMONs) were successfully synthesized by a combination of hyper-crosslinking mediated self-assembly process and a post-modification strategy. Benefiting from amino groups and hollow microporous structure, the resultant NH2-HMONs can be used to immobilize Pd nanoparticles (Pd@NH2-HMONs) and enhance the adsorption capacity for iodine. The obtained Pd@NH2-HMONs exhibited outstanding catalytic activity for hydrogenation of nitroarenes to aniline analogues. This strategy represents a new method for the preparation of porous organic polymers with special morphologies and functionalizations for potential applications including adsorption, separation, and catalysis.

KW - I uptake

KW - amino-functionalization

KW - hollow microporous organic nanospheres

KW - supported Pd nanoparticles

UR - https://www.scopus.com/pages/publications/85052652724

U2 - 10.1002/pola.29092

DO - 10.1002/pola.29092

M3 - 文章

AN - SCOPUS:85052652724

SN - 0887-624X

VL - 56

SP - 2045

EP - 2052

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 18

ER -

Amino-functionalized hollow microporous organic nanospheres for pd supported catalysis and I₂ uptake

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this