Aldehyde-Tagged Zirconium Metal-Organic Frameworks: A Versatile Platform for Postsynthetic Modification

Fu Gui Xi; Hui Liu; Ning Ning Yang; En Qing Gao

doi:10.1021/acs.inorgchem.6b00598

Aldehyde-Tagged Zirconium Metal-Organic Frameworks: A Versatile Platform for Postsynthetic Modification

Fu Gui Xi
, Hui Liu
, Ning Ning Yang
, En Qing Gao^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

Aldehyde-tagged UiO-67-type metal-organic frameworks (MOFs) have been synthesized via the direct solvothermal method or postsynthetic ligand exchange. Various functionalities have been introduced into the MOFs via postsynthetic modification (PSM) employing C-N and C-C coupling reactions of the aldehyde tag. Tandem PSM has also been demonstrated. An amino-functionalized MOF obtained by PSM is shown to be an efficient, heterogeneous, and recyclable catalyst for Knoevenagel condensation.

Original language	English
Pages (from-to)	4701-4703
Number of pages	3
Journal	Inorganic Chemistry
Volume	55
Issue number	10
DOIs	https://doi.org/10.1021/acs.inorgchem.6b00598
State	Published - 16 May 2016

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title = "Aldehyde-Tagged Zirconium Metal-Organic Frameworks: A Versatile Platform for Postsynthetic Modification",

abstract = "Aldehyde-tagged UiO-67-type metal-organic frameworks (MOFs) have been synthesized via the direct solvothermal method or postsynthetic ligand exchange. Various functionalities have been introduced into the MOFs via postsynthetic modification (PSM) employing C-N and C-C coupling reactions of the aldehyde tag. Tandem PSM has also been demonstrated. An amino-functionalized MOF obtained by PSM is shown to be an efficient, heterogeneous, and recyclable catalyst for Knoevenagel condensation.",

author = "Xi, \{Fu Gui\} and Hui Liu and Yang, \{Ning Ning\} and Gao, \{En Qing\}",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

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doi = "10.1021/acs.inorgchem.6b00598",

language = "英语",

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T1 - Aldehyde-Tagged Zirconium Metal-Organic Frameworks

T2 - A Versatile Platform for Postsynthetic Modification

AU - Xi, Fu Gui

AU - Liu, Hui

AU - Yang, Ning Ning

AU - Gao, En Qing

PY - 2016/5/16

Y1 - 2016/5/16

N2 - Aldehyde-tagged UiO-67-type metal-organic frameworks (MOFs) have been synthesized via the direct solvothermal method or postsynthetic ligand exchange. Various functionalities have been introduced into the MOFs via postsynthetic modification (PSM) employing C-N and C-C coupling reactions of the aldehyde tag. Tandem PSM has also been demonstrated. An amino-functionalized MOF obtained by PSM is shown to be an efficient, heterogeneous, and recyclable catalyst for Knoevenagel condensation.

AB - Aldehyde-tagged UiO-67-type metal-organic frameworks (MOFs) have been synthesized via the direct solvothermal method or postsynthetic ligand exchange. Various functionalities have been introduced into the MOFs via postsynthetic modification (PSM) employing C-N and C-C coupling reactions of the aldehyde tag. Tandem PSM has also been demonstrated. An amino-functionalized MOF obtained by PSM is shown to be an efficient, heterogeneous, and recyclable catalyst for Knoevenagel condensation.

UR - https://www.scopus.com/pages/publications/84969851233

U2 - 10.1021/acs.inorgchem.6b00598

DO - 10.1021/acs.inorgchem.6b00598

M3 - 文章

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SN - 0020-1669

VL - 55

SP - 4701

EP - 4703

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 10

ER -

Aldehyde-Tagged Zirconium Metal-Organic Frameworks: A Versatile Platform for Postsynthetic Modification

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