Aerobic oxidation of alcohol in aqueous solution catalyzed by gold

Huanrong Li; Bingtao Guan; Wenjin Wang; Dong Xing; Zhao Fang; Xiaobing Wan; Liping Yang; Zhangjie Shi

doi:10.1016/j.tet.2007.05.117

Aerobic oxidation of alcohol in aqueous solution catalyzed by gold

Huanrong Li
, Bingtao Guan
, Wenjin Wang
, Dong Xing
, Zhao Fang
, Xiaobing Wan
, Liping Yang
, Zhangjie Shi^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Peking University
East China Normal University
Chinese Academy of Sciences

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

The heterogeneous oxidation catalyzed by supported gold nanoparticles has been relatively well studied. In comparison, the oxidation of alcohols catalyzed by ligand-supported gold complexes was rarely reported. Herein a general method is demonstrated to oxidize secondary and primary benzyl and allylic alcohols to carbonyl compounds via Au(I) catalyzed reaction in air and water. Primary mechanistic studies indicated that the catalytic pathway is different from those catalyzed by solid-supported gold nanoparticles.

Original language	English
Pages (from-to)	8430-8434
Number of pages	5
Journal	Tetrahedron
Volume	63
Issue number	35
DOIs	https://doi.org/10.1016/j.tet.2007.05.117
State	Published - 27 Aug 2007

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10.1016/j.tet.2007.05.117

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title = "Aerobic oxidation of alcohol in aqueous solution catalyzed by gold",

abstract = "The heterogeneous oxidation catalyzed by supported gold nanoparticles has been relatively well studied. In comparison, the oxidation of alcohols catalyzed by ligand-supported gold complexes was rarely reported. Herein a general method is demonstrated to oxidize secondary and primary benzyl and allylic alcohols to carbonyl compounds via Au(I) catalyzed reaction in air and water. Primary mechanistic studies indicated that the catalytic pathway is different from those catalyzed by solid-supported gold nanoparticles.",

author = "Huanrong Li and Bingtao Guan and Wenjin Wang and Dong Xing and Zhao Fang and Xiaobing Wan and Liping Yang and Zhangjie Shi",

year = "2007",

month = aug,

day = "27",

doi = "10.1016/j.tet.2007.05.117",

language = "英语",

volume = "63",

pages = "8430--8434",

journal = "Tetrahedron",

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TY - JOUR

T1 - Aerobic oxidation of alcohol in aqueous solution catalyzed by gold

AU - Li, Huanrong

AU - Guan, Bingtao

AU - Wang, Wenjin

AU - Xing, Dong

AU - Fang, Zhao

AU - Wan, Xiaobing

AU - Yang, Liping

AU - Shi, Zhangjie

PY - 2007/8/27

Y1 - 2007/8/27

N2 - The heterogeneous oxidation catalyzed by supported gold nanoparticles has been relatively well studied. In comparison, the oxidation of alcohols catalyzed by ligand-supported gold complexes was rarely reported. Herein a general method is demonstrated to oxidize secondary and primary benzyl and allylic alcohols to carbonyl compounds via Au(I) catalyzed reaction in air and water. Primary mechanistic studies indicated that the catalytic pathway is different from those catalyzed by solid-supported gold nanoparticles.

AB - The heterogeneous oxidation catalyzed by supported gold nanoparticles has been relatively well studied. In comparison, the oxidation of alcohols catalyzed by ligand-supported gold complexes was rarely reported. Herein a general method is demonstrated to oxidize secondary and primary benzyl and allylic alcohols to carbonyl compounds via Au(I) catalyzed reaction in air and water. Primary mechanistic studies indicated that the catalytic pathway is different from those catalyzed by solid-supported gold nanoparticles.

UR - https://www.scopus.com/pages/publications/34447530637

U2 - 10.1016/j.tet.2007.05.117

DO - 10.1016/j.tet.2007.05.117

M3 - 文章

AN - SCOPUS:34447530637

SN - 0040-4020

VL - 63

SP - 8430

EP - 8434

JO - Tetrahedron

JF - Tetrahedron

IS - 35

ER -

Aerobic oxidation of alcohol in aqueous solution catalyzed by gold

Abstract

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