Acid- and base-functionalized core-confined bottlebrush copolymer catalysts for one-pot cascade reactions

Linfeng Xiong; Hui Zhang; Aiqing Zhong; Zidong He; Kun Huang

doi:10.1039/c4cc06573e

Acid- and base-functionalized core-confined bottlebrush copolymer catalysts for one-pot cascade reactions

Linfeng Xiong
, Hui Zhang
, Aiqing Zhong
, Zidong He
, Kun Huang^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

We demonstrate a novel method that enables the formation of core-confined bottlebrush copolymers (CCBCs) as catalyst supports. Significantly, owing to the site-isolated effect, these CCBC catalysts with the incompatible acidic para-toluenesulfonic acid (PTSA) and basic 4-(dimethylamino)pyridine (DMAP) groups can conduct a simple two-step sequential reaction in one vessel.

Original language	English
Pages (from-to)	14778-14781
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	94
DOIs	https://doi.org/10.1039/c4cc06573e
State	Published - 30 Oct 2014

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title = "Acid- and base-functionalized core-confined bottlebrush copolymer catalysts for one-pot cascade reactions",

abstract = "We demonstrate a novel method that enables the formation of core-confined bottlebrush copolymers (CCBCs) as catalyst supports. Significantly, owing to the site-isolated effect, these CCBC catalysts with the incompatible acidic para-toluenesulfonic acid (PTSA) and basic 4-(dimethylamino)pyridine (DMAP) groups can conduct a simple two-step sequential reaction in one vessel.",

author = "Linfeng Xiong and Hui Zhang and Aiqing Zhong and Zidong He and Kun Huang",

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T1 - Acid- and base-functionalized core-confined bottlebrush copolymer catalysts for one-pot cascade reactions

AU - Xiong, Linfeng

AU - Zhang, Hui

AU - Zhong, Aiqing

AU - He, Zidong

AU - Huang, Kun

PY - 2014/10/30

Y1 - 2014/10/30

N2 - We demonstrate a novel method that enables the formation of core-confined bottlebrush copolymers (CCBCs) as catalyst supports. Significantly, owing to the site-isolated effect, these CCBC catalysts with the incompatible acidic para-toluenesulfonic acid (PTSA) and basic 4-(dimethylamino)pyridine (DMAP) groups can conduct a simple two-step sequential reaction in one vessel.

AB - We demonstrate a novel method that enables the formation of core-confined bottlebrush copolymers (CCBCs) as catalyst supports. Significantly, owing to the site-isolated effect, these CCBC catalysts with the incompatible acidic para-toluenesulfonic acid (PTSA) and basic 4-(dimethylamino)pyridine (DMAP) groups can conduct a simple two-step sequential reaction in one vessel.

UR - https://www.scopus.com/pages/publications/84908628168

U2 - 10.1039/c4cc06573e

DO - 10.1039/c4cc06573e

M3 - 文章

AN - SCOPUS:84908628168

SN - 1359-7345

VL - 50

SP - 14778

EP - 14781

JO - Chemical Communications

JF - Chemical Communications

IS - 94

ER -

Acid- and base-functionalized core-confined bottlebrush copolymer catalysts for one-pot cascade reactions

Abstract

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