A Titanosilicate That Is Structurally Analogous to an MWW-Type Lamellar Precursor

Weibin Fan; Peng Wu; Seitaro Namba; Takashi Tatsumi

doi:10.1002/anie.200352723

A Titanosilicate That Is Structurally Analogous to an MWW-Type Lamellar Precursor

Weibin Fan
, Peng Wu
, Seitaro Namba
, Takashi Tatsumi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

155 Scopus citations

Abstract

With an analogous structure to an MWW lamellar precursor, a titanosilicate (denoted Ti-YNU-1) has been developed by using a postsynthetic acid-treatment and calcination procedure (see scheme). The material behaves as a large-pore zeolite, showing high activity, selectivity, and stability towards the liquid-phase epoxidation of bulky cycloalkenes using H₂O₂ as an oxidant.

Original language	English
Pages (from-to)	236-240
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	2
DOIs	https://doi.org/10.1002/anie.200352723
State	Published - 29 Dec 2003
Externally published	Yes

Keywords

Alkenes
Epoxidation
Heterogeneous catalysis
Titanosilicates
Zeolites

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10.1002/anie.200352723

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abstract = "With an analogous structure to an MWW lamellar precursor, a titanosilicate (denoted Ti-YNU-1) has been developed by using a postsynthetic acid-treatment and calcination procedure (see scheme). The material behaves as a large-pore zeolite, showing high activity, selectivity, and stability towards the liquid-phase epoxidation of bulky cycloalkenes using H2O2 as an oxidant.",

keywords = "Alkenes, Epoxidation, Heterogeneous catalysis, Titanosilicates, Zeolites",

author = "Weibin Fan and Peng Wu and Seitaro Namba and Takashi Tatsumi",

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AU - Fan, Weibin

AU - Wu, Peng

AU - Namba, Seitaro

AU - Tatsumi, Takashi

PY - 2003/12/29

Y1 - 2003/12/29

N2 - With an analogous structure to an MWW lamellar precursor, a titanosilicate (denoted Ti-YNU-1) has been developed by using a postsynthetic acid-treatment and calcination procedure (see scheme). The material behaves as a large-pore zeolite, showing high activity, selectivity, and stability towards the liquid-phase epoxidation of bulky cycloalkenes using H2O2 as an oxidant.

AB - With an analogous structure to an MWW lamellar precursor, a titanosilicate (denoted Ti-YNU-1) has been developed by using a postsynthetic acid-treatment and calcination procedure (see scheme). The material behaves as a large-pore zeolite, showing high activity, selectivity, and stability towards the liquid-phase epoxidation of bulky cycloalkenes using H2O2 as an oxidant.

KW - Alkenes

KW - Epoxidation

KW - Heterogeneous catalysis

KW - Titanosilicates

KW - Zeolites

UR - https://www.scopus.com/pages/publications/0345862301

U2 - 10.1002/anie.200352723

DO - 10.1002/anie.200352723

M3 - 文章

AN - SCOPUS:0345862301

SN - 1433-7851

VL - 43

SP - 236

EP - 240

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 2

ER -

A Titanosilicate That Is Structurally Analogous to an MWW-Type Lamellar Precursor

Abstract

Keywords

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