A three-dimensional manganese(II) complex exhibiting ferrimagnetic and metamagnetic behaviors

Ruihu Wang; Enqing Gao; Maochun Hong; Song Gao; Junhua Luo; Zhenzhong Lin; Lei Han; Rong Cao

doi:10.1021/ic034550k

A three-dimensional manganese(II) complex exhibiting ferrimagnetic and metamagnetic behaviors

Ruihu Wang
, Enqing Gao
, Maochun Hong^*
, Song Gao
, Junhua Luo
, Zhenzhong Lin
, Lei Han
, Rong Cao

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

94 Scopus citations

Abstract

A three-dimensional complex, [Mn₃(4-aba)₆] _n (1) (4-Haba = 4-aminobenzoic acid), consisting of manganese(II) chains and 4-aba bridging ligands, has been synthesized and characterized. Magnetic studies show that the compound behaves as a three-dimensional metamagnet built of homometallic ferrimagnetic chains. The required noncompensation in spin moments is achieved by alternating interactions in an AF-AF-F sequence (AF = antiferromagnetic; F = ferromagnetic) by considering intrachain magnetic interactions.

Original language	English
Pages (from-to)	5486-5488
Number of pages	3
Journal	Inorganic Chemistry
Volume	42
Issue number	18
DOIs	https://doi.org/10.1021/ic034550k
State	Published - 8 Sep 2003
Externally published	Yes

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@article{550dabcd12364522bce26ec324019a6b,

title = "A three-dimensional manganese(II) complex exhibiting ferrimagnetic and metamagnetic behaviors",

abstract = "A three-dimensional complex, [Mn3(4-aba)6] n (1) (4-Haba = 4-aminobenzoic acid), consisting of manganese(II) chains and 4-aba bridging ligands, has been synthesized and characterized. Magnetic studies show that the compound behaves as a three-dimensional metamagnet built of homometallic ferrimagnetic chains. The required noncompensation in spin moments is achieved by alternating interactions in an AF-AF-F sequence (AF = antiferromagnetic; F = ferromagnetic) by considering intrachain magnetic interactions.",

author = "Ruihu Wang and Enqing Gao and Maochun Hong and Song Gao and Junhua Luo and Zhenzhong Lin and Lei Han and Rong Cao",

year = "2003",

month = sep,

day = "8",

doi = "10.1021/ic034550k",

language = "英语",

volume = "42",

pages = "5486--5488",

journal = "Inorganic Chemistry",

issn = "0020-1669",

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T1 - A three-dimensional manganese(II) complex exhibiting ferrimagnetic and metamagnetic behaviors

AU - Wang, Ruihu

AU - Gao, Enqing

AU - Hong, Maochun

AU - Gao, Song

AU - Luo, Junhua

AU - Lin, Zhenzhong

AU - Han, Lei

AU - Cao, Rong

PY - 2003/9/8

Y1 - 2003/9/8

N2 - A three-dimensional complex, [Mn3(4-aba)6] n (1) (4-Haba = 4-aminobenzoic acid), consisting of manganese(II) chains and 4-aba bridging ligands, has been synthesized and characterized. Magnetic studies show that the compound behaves as a three-dimensional metamagnet built of homometallic ferrimagnetic chains. The required noncompensation in spin moments is achieved by alternating interactions in an AF-AF-F sequence (AF = antiferromagnetic; F = ferromagnetic) by considering intrachain magnetic interactions.

AB - A three-dimensional complex, [Mn3(4-aba)6] n (1) (4-Haba = 4-aminobenzoic acid), consisting of manganese(II) chains and 4-aba bridging ligands, has been synthesized and characterized. Magnetic studies show that the compound behaves as a three-dimensional metamagnet built of homometallic ferrimagnetic chains. The required noncompensation in spin moments is achieved by alternating interactions in an AF-AF-F sequence (AF = antiferromagnetic; F = ferromagnetic) by considering intrachain magnetic interactions.

UR - https://www.scopus.com/pages/publications/0042877167

U2 - 10.1021/ic034550k

DO - 10.1021/ic034550k

M3 - 文章

AN - SCOPUS:0042877167

SN - 0020-1669

VL - 42

SP - 5486

EP - 5488

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 18

ER -

A three-dimensional manganese(II) complex exhibiting ferrimagnetic and metamagnetic behaviors

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