A strategy to control the grain boundary density and Cu+/Cu0 ratio of Cu-based catalysts for efficient electroreduction of CO2 to C2 products

Chunjun Chen; Xiaofu Sun; Xupeng Yan; Yahui Wu; Mingyang Liu; Shuaishuai Liu; Zhijuan Zhao; Buxing Han

doi:10.1039/d0gc00247j

A strategy to control the grain boundary density and Cu⁺/Cu⁰ ratio of Cu-based catalysts for efficient electroreduction of CO₂ to C2 products

Chunjun Chen
, Xiaofu Sun^*
, Xupeng Yan
, Yahui Wu
, Mingyang Liu
, Shuaishuai Liu
, Zhijuan Zhao
, Buxing Han

^*Corresponding author for this work

Chinese Academy of Sciences
University of Chinese Academy of Sciences
Huairou National Comprehensive Science Center
East China Normal University

Research output: Contribution to journal › Article › peer-review

71 Scopus citations

Abstract

Cu(OH)₂/CuO nanocomposite-derived Cu₂O/Cu was highly efficient for CO₂ electroreduction to C2 products. The highest faradaic efficiency and current density could reach 64.5% and 26.2 mA cm^-2, respectively. By changing the calcination time, moderate grain boundary density and the Cu⁺/Cu⁰ ratio in catalysts can be controlled, leading to a large number of active sites and low interfacial charge transfer resistance.

Original language	English
Pages (from-to)	1572-1576
Number of pages	5
Journal	Green Chemistry
Volume	22
Issue number	5
DOIs	https://doi.org/10.1039/d0gc00247j
State	Published - 7 Mar 2020
Externally published	Yes

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title = "A strategy to control the grain boundary density and Cu+/Cu0 ratio of Cu-based catalysts for efficient electroreduction of CO2 to C2 products",

abstract = "Cu(OH)2/CuO nanocomposite-derived Cu2O/Cu was highly efficient for CO2 electroreduction to C2 products. The highest faradaic efficiency and current density could reach 64.5\% and 26.2 mA cm-2, respectively. By changing the calcination time, moderate grain boundary density and the Cu+/Cu0 ratio in catalysts can be controlled, leading to a large number of active sites and low interfacial charge transfer resistance.",

author = "Chunjun Chen and Xiaofu Sun and Xupeng Yan and Yahui Wu and Mingyang Liu and Shuaishuai Liu and Zhijuan Zhao and Buxing Han",

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T1 - A strategy to control the grain boundary density and Cu+/Cu0 ratio of Cu-based catalysts for efficient electroreduction of CO2 to C2 products

AU - Chen, Chunjun

AU - Sun, Xiaofu

AU - Yan, Xupeng

AU - Wu, Yahui

AU - Liu, Mingyang

AU - Liu, Shuaishuai

AU - Zhao, Zhijuan

AU - Han, Buxing

PY - 2020/3/7

Y1 - 2020/3/7

N2 - Cu(OH)2/CuO nanocomposite-derived Cu2O/Cu was highly efficient for CO2 electroreduction to C2 products. The highest faradaic efficiency and current density could reach 64.5% and 26.2 mA cm-2, respectively. By changing the calcination time, moderate grain boundary density and the Cu+/Cu0 ratio in catalysts can be controlled, leading to a large number of active sites and low interfacial charge transfer resistance.

AB - Cu(OH)2/CuO nanocomposite-derived Cu2O/Cu was highly efficient for CO2 electroreduction to C2 products. The highest faradaic efficiency and current density could reach 64.5% and 26.2 mA cm-2, respectively. By changing the calcination time, moderate grain boundary density and the Cu+/Cu0 ratio in catalysts can be controlled, leading to a large number of active sites and low interfacial charge transfer resistance.

UR - https://www.scopus.com/pages/publications/85081740119

U2 - 10.1039/d0gc00247j

DO - 10.1039/d0gc00247j

M3 - 文章

AN - SCOPUS:85081740119

SN - 1463-9262

VL - 22

SP - 1572

EP - 1576

JO - Green Chemistry

JF - Green Chemistry

IS - 5

ER -

A strategy to control the grain boundary density and Cu⁺/Cu⁰ ratio of Cu-based catalysts for efficient electroreduction of CO₂ to C2 products

Abstract

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