A simple approach for synthesis of TAPO-11 molecular sieve with controllable space group

Yue Ming Liu; Huan Yan Zhang; Hai Jiao Zhang; Hai Hong Wu; Peng Wu; Ming Yuan He

A simple approach for synthesis of TAPO-11 molecular sieve with controllable space group

Yue Ming Liu^*
, Huan Yan Zhang
, Hai Jiao Zhang
, Hai Hong Wu
, Peng Wu
, Ming Yuan He

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

Abstract

A TAPO-11 molecular sieve with the space group Icm2 was synthesized successfully. The samples with different space group were controlled simply only by adjusting the crystallization temperature (CT) in the hydrothermal system. In the system of gel with a molar composition of 0.7R: xTiO₂: P ₂O₅: Al₂O₃: 30H₂O, where x is 0.01-0.10 and the R is a mixture of di-n-propylamine and diisopropylamine as templates. When CT was between 150-160°C, the calcined sample showed the space group of Icm2, while it showed Pna2₁ at CT larger than 190°C. The characterizations of UV-Vis and FT-IR confirmed that Ti was incorporated into the AEL framework successfully.

Original language	English
Pages (from-to)	1409-1412
Number of pages	4
Journal	Chinese Chemical Letters
Volume	17
Issue number	10
State	Published - Oct 2006

Keywords

Molecular sieve
Space group
Synthesis
TAPO-11
Titanosilicate

Cite this

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title = "A simple approach for synthesis of TAPO-11 molecular sieve with controllable space group",

abstract = "A TAPO-11 molecular sieve with the space group Icm2 was synthesized successfully. The samples with different space group were controlled simply only by adjusting the crystallization temperature (CT) in the hydrothermal system. In the system of gel with a molar composition of 0.7R: xTiO2: P 2O5: Al2O3: 30H2O, where x is 0.01-0.10 and the R is a mixture of di-n-propylamine and diisopropylamine as templates. When CT was between 150-160°C, the calcined sample showed the space group of Icm2, while it showed Pna21 at CT larger than 190°C. The characterizations of UV-Vis and FT-IR confirmed that Ti was incorporated into the AEL framework successfully.",

keywords = "Molecular sieve, Space group, Synthesis, TAPO-11, Titanosilicate",

author = "Liu, \{Yue Ming\} and Zhang, \{Huan Yan\} and Zhang, \{Hai Jiao\} and Wu, \{Hai Hong\} and Peng Wu and He, \{Ming Yuan\}",

year = "2006",

month = oct,

language = "英语",

volume = "17",

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journal = "Chinese Chemical Letters",

issn = "1001-8417",

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TY - JOUR

T1 - A simple approach for synthesis of TAPO-11 molecular sieve with controllable space group

AU - Liu, Yue Ming

AU - Zhang, Huan Yan

AU - Zhang, Hai Jiao

AU - Wu, Hai Hong

AU - Wu, Peng

AU - He, Ming Yuan

PY - 2006/10

Y1 - 2006/10

N2 - A TAPO-11 molecular sieve with the space group Icm2 was synthesized successfully. The samples with different space group were controlled simply only by adjusting the crystallization temperature (CT) in the hydrothermal system. In the system of gel with a molar composition of 0.7R: xTiO2: P 2O5: Al2O3: 30H2O, where x is 0.01-0.10 and the R is a mixture of di-n-propylamine and diisopropylamine as templates. When CT was between 150-160°C, the calcined sample showed the space group of Icm2, while it showed Pna21 at CT larger than 190°C. The characterizations of UV-Vis and FT-IR confirmed that Ti was incorporated into the AEL framework successfully.

AB - A TAPO-11 molecular sieve with the space group Icm2 was synthesized successfully. The samples with different space group were controlled simply only by adjusting the crystallization temperature (CT) in the hydrothermal system. In the system of gel with a molar composition of 0.7R: xTiO2: P 2O5: Al2O3: 30H2O, where x is 0.01-0.10 and the R is a mixture of di-n-propylamine and diisopropylamine as templates. When CT was between 150-160°C, the calcined sample showed the space group of Icm2, while it showed Pna21 at CT larger than 190°C. The characterizations of UV-Vis and FT-IR confirmed that Ti was incorporated into the AEL framework successfully.

KW - Molecular sieve

KW - Space group

KW - Synthesis

KW - TAPO-11

KW - Titanosilicate

UR - https://www.scopus.com/pages/publications/33751063641

M3 - 文章

AN - SCOPUS:33751063641

SN - 1001-8417

VL - 17

SP - 1409

EP - 1412

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 10

ER -

A simple approach for synthesis of TAPO-11 molecular sieve with controllable space group

Abstract

Keywords

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