A self-templated approach to TiO 2 microcapsules

  • Yongxing Hu
  • , Jianping Ge
  • , Yugang Sun
  • , Tierui Zhang
  • , Yadong Yin*
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

143 Scopus citations

Abstract

A self-templated approach has been developed for the synthesis of TiO 2 microcapsules with tunable size and wall thickness by heating sol-gel derived TiO 2 microspheres with poly(acrylic acid) (PAA) in a diethylene glycol (DEG) solution. PAA plays a crucial role in the formation of microcapsules by crosslinking the surface TiO 2 nanoparticles and preventing them from dissolution by DEG. Hollow microcapsules form when DEG molecules penetrate the outer layer and remove the core materials by forming soluble titanium glycolate.

Original languageEnglish
Pages (from-to)1832-1836
Number of pages5
JournalNano Letters
Volume7
Issue number6
DOIs
StatePublished - Jun 2007
Externally publishedYes

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