Abstract
A self-templated approach has been developed for the synthesis of TiO 2 microcapsules with tunable size and wall thickness by heating sol-gel derived TiO 2 microspheres with poly(acrylic acid) (PAA) in a diethylene glycol (DEG) solution. PAA plays a crucial role in the formation of microcapsules by crosslinking the surface TiO 2 nanoparticles and preventing them from dissolution by DEG. Hollow microcapsules form when DEG molecules penetrate the outer layer and remove the core materials by forming soluble titanium glycolate.
| Original language | English |
|---|---|
| Pages (from-to) | 1832-1836 |
| Number of pages | 5 |
| Journal | Nano Letters |
| Volume | 7 |
| Issue number | 6 |
| DOIs | |
| State | Published - Jun 2007 |
| Externally published | Yes |