A rhodium-catalyzed ylide formation/Smiles rearrangement reaction of chalcogenide ether and triazoles

Jiafeng He; Xun Shen Liu; Mingjia Li; Shaoting Peng; Zhi Yao Si; Lu Liu

doi:10.1039/d3qo00125c

A rhodium-catalyzed ylide formation/Smiles rearrangement reaction of chalcogenide ether and triazoles

Jiafeng He
, Xun Shen Liu
, Mingjia Li
, Shaoting Peng
, Zhi Yao Si
, Lu Liu^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A Rh(ii)-catalyzed highly stereoselective chalcogenide ylide formation/Smiles rearrangement reaction of diaryl thioether/selenoethers and triazoles was successfully developed, which provided an efficient strategy to construct trisubstituted acyclic vinyl sulfides/selenides. The salient features of this protocol include simple operation, readily available starting materials, atom economy, broad substrate scope, and convenient transformation of products.

Original language	English
Pages (from-to)	2198-2203
Number of pages	6
Journal	Organic Chemistry Frontiers
Volume	10
Issue number	9
DOIs	https://doi.org/10.1039/d3qo00125c
State	Published - 24 Mar 2023

Access to Document

10.1039/d3qo00125c

Cite this

@article{db43013e9fd74ac08c42cff9ea64647e,

title = "A rhodium-catalyzed ylide formation/Smiles rearrangement reaction of chalcogenide ether and triazoles",

abstract = "A Rh(ii)-catalyzed highly stereoselective chalcogenide ylide formation/Smiles rearrangement reaction of diaryl thioether/selenoethers and triazoles was successfully developed, which provided an efficient strategy to construct trisubstituted acyclic vinyl sulfides/selenides. The salient features of this protocol include simple operation, readily available starting materials, atom economy, broad substrate scope, and convenient transformation of products.",

author = "Jiafeng He and Liu, \{Xun Shen\} and Mingjia Li and Shaoting Peng and Si, \{Zhi Yao\} and Lu Liu",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2023",

month = mar,

day = "24",

doi = "10.1039/d3qo00125c",

language = "英语",

volume = "10",

pages = "2198--2203",

journal = "Organic Chemistry Frontiers",

issn = "2052-4110",

publisher = "Royal Society of Chemistry",

number = "9",

}

TY - JOUR

T1 - A rhodium-catalyzed ylide formation/Smiles rearrangement reaction of chalcogenide ether and triazoles

AU - He, Jiafeng

AU - Liu, Xun Shen

AU - Li, Mingjia

AU - Peng, Shaoting

AU - Si, Zhi Yao

AU - Liu, Lu

PY - 2023/3/24

Y1 - 2023/3/24

N2 - A Rh(ii)-catalyzed highly stereoselective chalcogenide ylide formation/Smiles rearrangement reaction of diaryl thioether/selenoethers and triazoles was successfully developed, which provided an efficient strategy to construct trisubstituted acyclic vinyl sulfides/selenides. The salient features of this protocol include simple operation, readily available starting materials, atom economy, broad substrate scope, and convenient transformation of products.

AB - A Rh(ii)-catalyzed highly stereoselective chalcogenide ylide formation/Smiles rearrangement reaction of diaryl thioether/selenoethers and triazoles was successfully developed, which provided an efficient strategy to construct trisubstituted acyclic vinyl sulfides/selenides. The salient features of this protocol include simple operation, readily available starting materials, atom economy, broad substrate scope, and convenient transformation of products.

UR - https://www.scopus.com/pages/publications/85151811519

U2 - 10.1039/d3qo00125c

DO - 10.1039/d3qo00125c

M3 - 文章

AN - SCOPUS:85151811519

SN - 2052-4110

VL - 10

SP - 2198

EP - 2203

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 9

ER -

A rhodium-catalyzed ylide formation/Smiles rearrangement reaction of chalcogenide ether and triazoles

Abstract

Access to Document

Other files and links

Fingerprint

Cite this