A Rh(II)-catalyzed three-component reaction of 3-diazooxindoles with: N, N -disubstituted anilines and glyoxylates for the synthesis of 3-aryl-3-substituted oxindoles

Shi Kun Jia; Long Long Song; Yu Bing Lei; A. Gopi Krishna Reddy; Dong Xing; Wen Hao Hu

doi:10.1039/c6ob01907b

A Rh(II)-catalyzed three-component reaction of 3-diazooxindoles with: N, N -disubstituted anilines and glyoxylates for the synthesis of 3-aryl-3-substituted oxindoles

Shi Kun Jia
, Long Long Song
, Yu Bing Lei
, A. Gopi Krishna Reddy
, Dong Xing
, Wen Hao Hu^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A simple and effective method for the synthesis of 3-aryl-3-substituted oxindole derivatives via a [Rh]-catalyzed three-component reaction of 3-diazooxindoles with N,N-disubstituted anilines and glyoxylates is developed. This transformation is proposed to proceed through an intermolecular aldol-type trapping of zwitterionic intermediates.

Original language	English
Pages (from-to)	10157-10160
Number of pages	4
Journal	Organic and Biomolecular Chemistry
Volume	14
Issue number	43
DOIs	https://doi.org/10.1039/c6ob01907b
State	Published - 2016

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title = "A Rh(II)-catalyzed three-component reaction of 3-diazooxindoles with: N, N -disubstituted anilines and glyoxylates for the synthesis of 3-aryl-3-substituted oxindoles",

abstract = "A simple and effective method for the synthesis of 3-aryl-3-substituted oxindole derivatives via a [Rh]-catalyzed three-component reaction of 3-diazooxindoles with N,N-disubstituted anilines and glyoxylates is developed. This transformation is proposed to proceed through an intermolecular aldol-type trapping of zwitterionic intermediates.",

author = "Jia, \{Shi Kun\} and Song, \{Long Long\} and Lei, \{Yu Bing\} and \{Gopi Krishna Reddy\}, A. and Dong Xing and Hu, \{Wen Hao\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

doi = "10.1039/c6ob01907b",

language = "英语",

volume = "14",

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journal = "Organic and Biomolecular Chemistry",

issn = "1477-0520",

publisher = "Royal Society of Chemistry",

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T1 - A Rh(II)-catalyzed three-component reaction of 3-diazooxindoles with

T2 - N, N -disubstituted anilines and glyoxylates for the synthesis of 3-aryl-3-substituted oxindoles

AU - Jia, Shi Kun

AU - Song, Long Long

AU - Lei, Yu Bing

AU - Gopi Krishna Reddy, A.

AU - Xing, Dong

AU - Hu, Wen Hao

PY - 2016

Y1 - 2016

N2 - A simple and effective method for the synthesis of 3-aryl-3-substituted oxindole derivatives via a [Rh]-catalyzed three-component reaction of 3-diazooxindoles with N,N-disubstituted anilines and glyoxylates is developed. This transformation is proposed to proceed through an intermolecular aldol-type trapping of zwitterionic intermediates.

AB - A simple and effective method for the synthesis of 3-aryl-3-substituted oxindole derivatives via a [Rh]-catalyzed three-component reaction of 3-diazooxindoles with N,N-disubstituted anilines and glyoxylates is developed. This transformation is proposed to proceed through an intermolecular aldol-type trapping of zwitterionic intermediates.

UR - https://www.scopus.com/pages/publications/84994618805

U2 - 10.1039/c6ob01907b

DO - 10.1039/c6ob01907b

M3 - 文章

AN - SCOPUS:84994618805

SN - 1477-0520

VL - 14

SP - 10157

EP - 10160

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 43

ER -

A Rh(II)-catalyzed three-component reaction of 3-diazooxindoles with: N, N -disubstituted anilines and glyoxylates for the synthesis of 3-aryl-3-substituted oxindoles

Abstract

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