A photoluminescent 8-fold [4 + 4] interpenetrating diamond network formed through strong hydrogen bonds

Qi Yue; Xiong Bing Qian; Li Yan; En Qing Gao

doi:10.1016/j.inoche.2008.05.027

A photoluminescent 8-fold [4 + 4] interpenetrating diamond network formed through strong hydrogen bonds

Qi Yue
, Xiong Bing Qian
, Li Yan
, En Qing Gao^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

A new complex with a hydrogen-bonded diamond network, [Zn(2,2′-bipy)₂(HBBDC)₂] (1) has been synthesized by the assembly of H₂BBDC, Zn(II) and 2,2′-bipy (H₂BBDC = bibenzyl-4,4′-dicarboxylic acid and 2,2′-bipy = 2,2′-bipyridine). The coordination of two 2,2′-bipy ligands and two carboxylate groups around Zn(II) interplays with the hydrogen-bonding involving the deprotonated and protonated carboxylate, making the mononuclear molecule an unusual supramolecular tetrahedral building unit for the diamond network. The long bridging ligand leads to 8-fold interpenetration of the net in the abnormal [4 + 4] mode. Compound 1 shows a strong fluorescent emission at 400 nm in solid state at room temperature.

Original language	English
Pages (from-to)	1067-1070
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	11
Issue number	9
DOIs	https://doi.org/10.1016/j.inoche.2008.05.027
State	Published - Sep 2008

Keywords

Diamond network
Hydrogen bonds
Interpenetration
Luminescence
Zinc(II) complex

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10.1016/j.inoche.2008.05.027

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@article{4151f033a1cc48e08b3e81ed1abfbab7,

title = "A photoluminescent 8-fold [4 + 4] interpenetrating diamond network formed through strong hydrogen bonds",

abstract = "A new complex with a hydrogen-bonded diamond network, [Zn(2,2′-bipy)2(HBBDC)2] (1) has been synthesized by the assembly of H2BBDC, Zn(II) and 2,2′-bipy (H2BBDC = bibenzyl-4,4′-dicarboxylic acid and 2,2′-bipy = 2,2′-bipyridine). The coordination of two 2,2′-bipy ligands and two carboxylate groups around Zn(II) interplays with the hydrogen-bonding involving the deprotonated and protonated carboxylate, making the mononuclear molecule an unusual supramolecular tetrahedral building unit for the diamond network. The long bridging ligand leads to 8-fold interpenetration of the net in the abnormal [4 + 4] mode. Compound 1 shows a strong fluorescent emission at 400 nm in solid state at room temperature.",

keywords = "Diamond network, Hydrogen bonds, Interpenetration, Luminescence, Zinc(II) complex",

author = "Qi Yue and Qian, \{Xiong Bing\} and Li Yan and Gao, \{En Qing\}",

year = "2008",

month = sep,

doi = "10.1016/j.inoche.2008.05.027",

language = "英语",

volume = "11",

pages = "1067--1070",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "9",

}

TY - JOUR

T1 - A photoluminescent 8-fold [4 + 4] interpenetrating diamond network formed through strong hydrogen bonds

AU - Yue, Qi

AU - Qian, Xiong Bing

AU - Yan, Li

AU - Gao, En Qing

PY - 2008/9

Y1 - 2008/9

N2 - A new complex with a hydrogen-bonded diamond network, [Zn(2,2′-bipy)2(HBBDC)2] (1) has been synthesized by the assembly of H2BBDC, Zn(II) and 2,2′-bipy (H2BBDC = bibenzyl-4,4′-dicarboxylic acid and 2,2′-bipy = 2,2′-bipyridine). The coordination of two 2,2′-bipy ligands and two carboxylate groups around Zn(II) interplays with the hydrogen-bonding involving the deprotonated and protonated carboxylate, making the mononuclear molecule an unusual supramolecular tetrahedral building unit for the diamond network. The long bridging ligand leads to 8-fold interpenetration of the net in the abnormal [4 + 4] mode. Compound 1 shows a strong fluorescent emission at 400 nm in solid state at room temperature.

AB - A new complex with a hydrogen-bonded diamond network, [Zn(2,2′-bipy)2(HBBDC)2] (1) has been synthesized by the assembly of H2BBDC, Zn(II) and 2,2′-bipy (H2BBDC = bibenzyl-4,4′-dicarboxylic acid and 2,2′-bipy = 2,2′-bipyridine). The coordination of two 2,2′-bipy ligands and two carboxylate groups around Zn(II) interplays with the hydrogen-bonding involving the deprotonated and protonated carboxylate, making the mononuclear molecule an unusual supramolecular tetrahedral building unit for the diamond network. The long bridging ligand leads to 8-fold interpenetration of the net in the abnormal [4 + 4] mode. Compound 1 shows a strong fluorescent emission at 400 nm in solid state at room temperature.

KW - Diamond network

KW - Hydrogen bonds

KW - Interpenetration

KW - Luminescence

KW - Zinc(II) complex

UR - https://www.scopus.com/pages/publications/50249087423

U2 - 10.1016/j.inoche.2008.05.027

DO - 10.1016/j.inoche.2008.05.027

M3 - 文章

AN - SCOPUS:50249087423

SN - 1387-7003

VL - 11

SP - 1067

EP - 1070

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 9

ER -

A photoluminescent 8-fold [4 + 4] interpenetrating diamond network formed through strong hydrogen bonds

Abstract

Keywords

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