A photo-induced C-C bond formation methodology to construct tetrahydrofluorenones and their related structures

Shujun Cai; Zheming Xiao; Jinjie Ou; Yingbo Shi; Shuanhu Gao

doi:10.1039/c5qo00392j

A photo-induced C-C bond formation methodology to construct tetrahydrofluorenones and their related structures

Shujun Cai, Zheming Xiao, Jinjie Ou, Yingbo Shi, Shuanhu Gao

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

A metal-free, photo-induced C-C bond formation methodology was developed to construct tetrahydrofluorenones and their related structures. This mild and efficient method proceeds either through electrocyclization or radical cyclization from β-Cl or β-Br aryl vinyl ketone. We believe that this method is particularly useful for the synthesis of related tetrahydrofluorenone containing natural products.

Original language	English
Pages (from-to)	354-358
Number of pages	5
Journal	Organic Chemistry Frontiers
Volume	3
Issue number	3
DOIs	https://doi.org/10.1039/c5qo00392j
State	Published - Mar 2016

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title = "A photo-induced C-C bond formation methodology to construct tetrahydrofluorenones and their related structures",

abstract = "A metal-free, photo-induced C-C bond formation methodology was developed to construct tetrahydrofluorenones and their related structures. This mild and efficient method proceeds either through electrocyclization or radical cyclization from β-Cl or β-Br aryl vinyl ketone. We believe that this method is particularly useful for the synthesis of related tetrahydrofluorenone containing natural products.",

author = "Shujun Cai and Zheming Xiao and Jinjie Ou and Yingbo Shi and Shuanhu Gao",

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T1 - A photo-induced C-C bond formation methodology to construct tetrahydrofluorenones and their related structures

AU - Cai, Shujun

AU - Xiao, Zheming

AU - Ou, Jinjie

AU - Shi, Yingbo

AU - Gao, Shuanhu

PY - 2016/3

Y1 - 2016/3

N2 - A metal-free, photo-induced C-C bond formation methodology was developed to construct tetrahydrofluorenones and their related structures. This mild and efficient method proceeds either through electrocyclization or radical cyclization from β-Cl or β-Br aryl vinyl ketone. We believe that this method is particularly useful for the synthesis of related tetrahydrofluorenone containing natural products.

AB - A metal-free, photo-induced C-C bond formation methodology was developed to construct tetrahydrofluorenones and their related structures. This mild and efficient method proceeds either through electrocyclization or radical cyclization from β-Cl or β-Br aryl vinyl ketone. We believe that this method is particularly useful for the synthesis of related tetrahydrofluorenone containing natural products.

UR - https://www.scopus.com/pages/publications/84958976303

U2 - 10.1039/c5qo00392j

DO - 10.1039/c5qo00392j

M3 - 文章

AN - SCOPUS:84958976303

SN - 2052-4110

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SP - 354

EP - 358

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 3

ER -

A photo-induced C-C bond formation methodology to construct tetrahydrofluorenones and their related structures

Abstract

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