A novel three-dimensional heterometallic compound: Templated assembly of the unprecedented planar "Na⊂[Cu4]" metalloporphyrin-like subunits

Yan Feng Yue, Bing Wu Wang, En Qing Gao, Chen Jie Fang, Cheng He, Chun Hua Yan

Research output: Contribution to journalArticlepeer-review

54 Scopus citations

Abstract

A 3D heterometallic compound, [Cu4Na4(TzDC) 4(H2O)7]n (H3TzDC = 1,2,3-triazole-4,5-dicarboxylic acid), which contains unprecedented planar "Na⊂[Cu4]" metalloporphyrin-like subunits, was synthesized by hydrothermal reactions involving in situ formation of the ligand and templated assembly of the metalloporphyrin-like subunits.

Original languageEnglish
Pages (from-to)2034-2036
Number of pages3
JournalChemical Communications
Issue number20
DOIs
StatePublished - 2007

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