A novel shape memory polynorbornene functionalized with poly(ε-caprolactone) side chain and cyano group through ring-opening metathesis polymerization

Dan Yang; Wei Huang; Jiahui Yu; Jisen Jiang; Liya Zhang; Meiran Xie

doi:10.1016/j.polymer.2010.09.009

A novel shape memory polynorbornene functionalized with poly(ε-caprolactone) side chain and cyano group through ring-opening metathesis polymerization

Dan Yang
, Wei Huang
, Jiahui Yu^*
, Jisen Jiang
, Liya Zhang
, Meiran Xie

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

65 Scopus citations

Abstract

A novel functionalized norbornene-based copolymer with long poly(ε-caprolactone) side chain and cyano group was synthesized in the combination of ring-opening polymerization and ring-opening metathesis polymerization, which was characterized by means of ¹H NMR, gel permeation chromatography, thermogravimetry, differential scanning calorimetry, wide-angle X-ray diffraction, and stress-strain measurements. The shape memory effect of the copolymer was evaluated by dynamical mechanical analysis, shape recovery ability, and shape recovery speed. Having the properties of the good shape fixity and the large shape recovery, the functionalized polynorbornene copolymer is expected to use as a potential shape memory material.

Original language	English
Pages (from-to)	5100-5106
Number of pages	7
Journal	Polymer
Volume	51
Issue number	22
DOIs	https://doi.org/10.1016/j.polymer.2010.09.009
State	Published - 15 Oct 2010

Keywords

Polynorbornene
Ring-opening metathesis polymerization (ROMP)
Shape memory polymer (SMP)

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10.1016/j.polymer.2010.09.009

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title = "A novel shape memory polynorbornene functionalized with poly(ε-caprolactone) side chain and cyano group through ring-opening metathesis polymerization",

abstract = "A novel functionalized norbornene-based copolymer with long poly(ε-caprolactone) side chain and cyano group was synthesized in the combination of ring-opening polymerization and ring-opening metathesis polymerization, which was characterized by means of 1H NMR, gel permeation chromatography, thermogravimetry, differential scanning calorimetry, wide-angle X-ray diffraction, and stress-strain measurements. The shape memory effect of the copolymer was evaluated by dynamical mechanical analysis, shape recovery ability, and shape recovery speed. Having the properties of the good shape fixity and the large shape recovery, the functionalized polynorbornene copolymer is expected to use as a potential shape memory material.",

keywords = "Polynorbornene, Ring-opening metathesis polymerization (ROMP), Shape memory polymer (SMP)",

author = "Dan Yang and Wei Huang and Jiahui Yu and Jisen Jiang and Liya Zhang and Meiran Xie",

year = "2010",

month = oct,

day = "15",

doi = "10.1016/j.polymer.2010.09.009",

language = "英语",

volume = "51",

pages = "5100--5106",

journal = "Polymer",

issn = "0032-3861",

publisher = "Elsevier B.V.",

number = "22",

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TY - JOUR

T1 - A novel shape memory polynorbornene functionalized with poly(ε-caprolactone) side chain and cyano group through ring-opening metathesis polymerization

AU - Yang, Dan

AU - Huang, Wei

AU - Yu, Jiahui

AU - Jiang, Jisen

AU - Zhang, Liya

AU - Xie, Meiran

PY - 2010/10/15

Y1 - 2010/10/15

N2 - A novel functionalized norbornene-based copolymer with long poly(ε-caprolactone) side chain and cyano group was synthesized in the combination of ring-opening polymerization and ring-opening metathesis polymerization, which was characterized by means of 1H NMR, gel permeation chromatography, thermogravimetry, differential scanning calorimetry, wide-angle X-ray diffraction, and stress-strain measurements. The shape memory effect of the copolymer was evaluated by dynamical mechanical analysis, shape recovery ability, and shape recovery speed. Having the properties of the good shape fixity and the large shape recovery, the functionalized polynorbornene copolymer is expected to use as a potential shape memory material.

AB - A novel functionalized norbornene-based copolymer with long poly(ε-caprolactone) side chain and cyano group was synthesized in the combination of ring-opening polymerization and ring-opening metathesis polymerization, which was characterized by means of 1H NMR, gel permeation chromatography, thermogravimetry, differential scanning calorimetry, wide-angle X-ray diffraction, and stress-strain measurements. The shape memory effect of the copolymer was evaluated by dynamical mechanical analysis, shape recovery ability, and shape recovery speed. Having the properties of the good shape fixity and the large shape recovery, the functionalized polynorbornene copolymer is expected to use as a potential shape memory material.

KW - Polynorbornene

KW - Ring-opening metathesis polymerization (ROMP)

KW - Shape memory polymer (SMP)

UR - https://www.scopus.com/pages/publications/77957878172

U2 - 10.1016/j.polymer.2010.09.009

DO - 10.1016/j.polymer.2010.09.009

M3 - 文章

AN - SCOPUS:77957878172

SN - 0032-3861

VL - 51

SP - 5100

EP - 5106

JO - Polymer

JF - Polymer

IS - 22

ER -

A novel shape memory polynorbornene functionalized with poly(ε-caprolactone) side chain and cyano group through ring-opening metathesis polymerization

Abstract

Keywords

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