A novel mixed-valence complex containing CoII2CoIII2 molecular squares with 4,5-imidazoledicarboxylate bridges

Chuan Feng Wang; En Qing Gao; Zheng He; Chun Hua Yan

doi:10.1039/b315357f

A novel mixed-valence complex containing Co^II₂Co^III₂ molecular squares with 4,5-imidazoledicarboxylate bridges

Chuan Feng Wang
, En Qing Gao^*
, Zheng He
, Chun Hua Yan

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

115 Scopus citations

Abstract

A heterometallic complex, Na₂[Co^II₂Co^III₂(IDC³⁻)₄(bipy)₄] ·12H₂O (bipy = 2,2′-bipyridine), in which mixed-valence tetranuclear squares with imidazoledicarboxylate (IDC³⁻) linkers are tethered into a unique chain through disodium units, is hydrothermally synthesized and structurally and magnetically characterized.

Original language	English
Pages (from-to)	720-721
Number of pages	2
Journal	Chemical Communications
Volume	4
Issue number	6
DOIs	https://doi.org/10.1039/b315357f
State	Published - 2004

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title = "A novel mixed-valence complex containing CoII2CoIII2 molecular squares with 4,5-imidazoledicarboxylate bridges",

abstract = "A heterometallic complex, Na2[CoII2CoIII2(IDC3−)4(bipy)4] ·12H2O (bipy = 2,2′-bipyridine), in which mixed-valence tetranuclear squares with imidazoledicarboxylate (IDC3−) linkers are tethered into a unique chain through disodium units, is hydrothermally synthesized and structurally and magnetically characterized.",

author = "Wang, \{Chuan Feng\} and Gao, \{En Qing\} and Zheng He and Yan, \{Chun Hua\}",

year = "2004",

doi = "10.1039/b315357f",

language = "英语",

volume = "4",

pages = "720--721",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "6",

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TY - JOUR

T1 - A novel mixed-valence complex containing CoII2CoIII2 molecular squares with 4,5-imidazoledicarboxylate bridges

AU - Wang, Chuan Feng

AU - Gao, En Qing

AU - He, Zheng

AU - Yan, Chun Hua

PY - 2004

Y1 - 2004

N2 - A heterometallic complex, Na2[CoII2CoIII2(IDC3−)4(bipy)4] ·12H2O (bipy = 2,2′-bipyridine), in which mixed-valence tetranuclear squares with imidazoledicarboxylate (IDC3−) linkers are tethered into a unique chain through disodium units, is hydrothermally synthesized and structurally and magnetically characterized.

AB - A heterometallic complex, Na2[CoII2CoIII2(IDC3−)4(bipy)4] ·12H2O (bipy = 2,2′-bipyridine), in which mixed-valence tetranuclear squares with imidazoledicarboxylate (IDC3−) linkers are tethered into a unique chain through disodium units, is hydrothermally synthesized and structurally and magnetically characterized.

UR - https://www.scopus.com/pages/publications/1842483577

U2 - 10.1039/b315357f

DO - 10.1039/b315357f

M3 - 文章

AN - SCOPUS:1842483577

SN - 1359-7345

VL - 4

SP - 720

EP - 721

JO - Chemical Communications

JF - Chemical Communications

IS - 6

ER -

A novel mixed-valence complex containing Co^II₂Co^III₂ molecular squares with 4,5-imidazoledicarboxylate bridges

Abstract

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