A novel inorganic-organic hybrid material: Hydrothermal synthesis and properties of [V6O12(CH3O)4(phen) 4·4H2O] (phen = 1,10-phenanthroline)

C. Dai; W. Mi; F. Yang; B. Chen; H. Ding; Y. Shan

doi:10.1080/00958970500270836

A novel inorganic-organic hybrid material: Hydrothermal synthesis and properties of [V₆O₁₂(CH₃O)₄(phen) ₄·4H₂O] (phen = 1,10-phenanthroline)

C. Dai
, W. Mi
, F. Yang
, B. Chen
, H. Ding
, Y. Shan^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

An oxo-vanadium cluster [V₆O₁₂(CH₃O) ₄(phen)₄·4H₂O] (phen = 1,10-phenanthroline) was synthesized hydrothermally and characterized by IR, XPS, TG-DTA and single crystal X-ray diffraction analysis. It crystallizes in the triclinic space group P1^-, with cell parameters a = 9.709(1), b = 11.701(1), c = 13.365(2) Å, α = 74.430(2)°, β = 77.073(2)°, γ = 87.982(2)°, V = 1425.0(3) Å³ , Z = 2. The crystal is built up as an organic-inorganic hybrid compound with an unusual oxo-vanadium skeleton and water molecules. Water molecules make up a tetramer linking neighboring oxo-vanadium clusters to form one-dimensional chains, and then further build up three-dimensional supramolecular arrays through the π-π stacking interactions of phen.

Original language	English
Pages (from-to)	317-324
Number of pages	8
Journal	Journal of Coordination Chemistry
Volume	59
Issue number	3
DOIs	https://doi.org/10.1080/00958970500270836
State	Published - 15 Feb 2006

Keywords

Hydrothermal Synthesis
Inorganic-organic hybrid
Phenanthroline
Vanadium oxides

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title = "A novel inorganic-organic hybrid material: Hydrothermal synthesis and properties of [V6O12(CH3O)4(phen) 4·4H2O] (phen = 1,10-phenanthroline)",

abstract = "An oxo-vanadium cluster [V6O12(CH3O) 4(phen)4·4H2O] (phen = 1,10-phenanthroline) was synthesized hydrothermally and characterized by IR, XPS, TG-DTA and single crystal X-ray diffraction analysis. It crystallizes in the triclinic space group P1-, with cell parameters a = 9.709(1), b = 11.701(1), c = 13.365(2) {\AA}, α = 74.430(2)°, β = 77.073(2)°, γ = 87.982(2)°, V = 1425.0(3) {\AA}3 , Z = 2. The crystal is built up as an organic-inorganic hybrid compound with an unusual oxo-vanadium skeleton and water molecules. Water molecules make up a tetramer linking neighboring oxo-vanadium clusters to form one-dimensional chains, and then further build up three-dimensional supramolecular arrays through the π-π stacking interactions of phen.",

keywords = "Hydrothermal Synthesis, Inorganic-organic hybrid, Phenanthroline, Vanadium oxides",

author = "C. Dai and W. Mi and F. Yang and B. Chen and H. Ding and Y. Shan",

year = "2006",

month = feb,

day = "15",

doi = "10.1080/00958970500270836",

language = "英语",

volume = "59",

pages = "317--324",

journal = "Journal of Coordination Chemistry",

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T1 - A novel inorganic-organic hybrid material

T2 - Hydrothermal synthesis and properties of [V6O12(CH3O)4(phen) 4·4H2O] (phen = 1,10-phenanthroline)

AU - Dai, C.

AU - Mi, W.

AU - Yang, F.

AU - Chen, B.

AU - Ding, H.

AU - Shan, Y.

PY - 2006/2/15

Y1 - 2006/2/15

N2 - An oxo-vanadium cluster [V6O12(CH3O) 4(phen)4·4H2O] (phen = 1,10-phenanthroline) was synthesized hydrothermally and characterized by IR, XPS, TG-DTA and single crystal X-ray diffraction analysis. It crystallizes in the triclinic space group P1-, with cell parameters a = 9.709(1), b = 11.701(1), c = 13.365(2) Å, α = 74.430(2)°, β = 77.073(2)°, γ = 87.982(2)°, V = 1425.0(3) Å3 , Z = 2. The crystal is built up as an organic-inorganic hybrid compound with an unusual oxo-vanadium skeleton and water molecules. Water molecules make up a tetramer linking neighboring oxo-vanadium clusters to form one-dimensional chains, and then further build up three-dimensional supramolecular arrays through the π-π stacking interactions of phen.

AB - An oxo-vanadium cluster [V6O12(CH3O) 4(phen)4·4H2O] (phen = 1,10-phenanthroline) was synthesized hydrothermally and characterized by IR, XPS, TG-DTA and single crystal X-ray diffraction analysis. It crystallizes in the triclinic space group P1-, with cell parameters a = 9.709(1), b = 11.701(1), c = 13.365(2) Å, α = 74.430(2)°, β = 77.073(2)°, γ = 87.982(2)°, V = 1425.0(3) Å3 , Z = 2. The crystal is built up as an organic-inorganic hybrid compound with an unusual oxo-vanadium skeleton and water molecules. Water molecules make up a tetramer linking neighboring oxo-vanadium clusters to form one-dimensional chains, and then further build up three-dimensional supramolecular arrays through the π-π stacking interactions of phen.

KW - Hydrothermal Synthesis

KW - Inorganic-organic hybrid

KW - Phenanthroline

KW - Vanadium oxides

UR - https://www.scopus.com/pages/publications/33644625980

U2 - 10.1080/00958970500270836

DO - 10.1080/00958970500270836

M3 - 文章

AN - SCOPUS:33644625980

SN - 0095-8972

VL - 59

SP - 317

EP - 324

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 3

ER -

A novel inorganic-organic hybrid material: Hydrothermal synthesis and properties of [V₆O₁₂(CH₃O)₄(phen) ₄·4H₂O] (phen = 1,10-phenanthroline)

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