TY - JOUR
T1 - A novel inorganic-organic hybrid material
T2 - Hydrothermal synthesis and properties of [V6O12(CH3O)4(phen) 4·4H2O] (phen = 1,10-phenanthroline)
AU - Dai, C.
AU - Mi, W.
AU - Yang, F.
AU - Chen, B.
AU - Ding, H.
AU - Shan, Y.
PY - 2006/2/15
Y1 - 2006/2/15
N2 - An oxo-vanadium cluster [V6O12(CH3O) 4(phen)4·4H2O] (phen = 1,10-phenanthroline) was synthesized hydrothermally and characterized by IR, XPS, TG-DTA and single crystal X-ray diffraction analysis. It crystallizes in the triclinic space group P1-, with cell parameters a = 9.709(1), b = 11.701(1), c = 13.365(2) Å, α = 74.430(2)°, β = 77.073(2)°, γ = 87.982(2)°, V = 1425.0(3) Å3 , Z = 2. The crystal is built up as an organic-inorganic hybrid compound with an unusual oxo-vanadium skeleton and water molecules. Water molecules make up a tetramer linking neighboring oxo-vanadium clusters to form one-dimensional chains, and then further build up three-dimensional supramolecular arrays through the π-π stacking interactions of phen.
AB - An oxo-vanadium cluster [V6O12(CH3O) 4(phen)4·4H2O] (phen = 1,10-phenanthroline) was synthesized hydrothermally and characterized by IR, XPS, TG-DTA and single crystal X-ray diffraction analysis. It crystallizes in the triclinic space group P1-, with cell parameters a = 9.709(1), b = 11.701(1), c = 13.365(2) Å, α = 74.430(2)°, β = 77.073(2)°, γ = 87.982(2)°, V = 1425.0(3) Å3 , Z = 2. The crystal is built up as an organic-inorganic hybrid compound with an unusual oxo-vanadium skeleton and water molecules. Water molecules make up a tetramer linking neighboring oxo-vanadium clusters to form one-dimensional chains, and then further build up three-dimensional supramolecular arrays through the π-π stacking interactions of phen.
KW - Hydrothermal Synthesis
KW - Inorganic-organic hybrid
KW - Phenanthroline
KW - Vanadium oxides
UR - https://www.scopus.com/pages/publications/33644625980
U2 - 10.1080/00958970500270836
DO - 10.1080/00958970500270836
M3 - 文章
AN - SCOPUS:33644625980
SN - 0095-8972
VL - 59
SP - 317
EP - 324
JO - Journal of Coordination Chemistry
JF - Journal of Coordination Chemistry
IS - 3
ER -