A novel hydrogen-bonded microporous framework constructed from two different metal complexes

En Qing Gao; Dai Zheng Liao; Zong Hui Jiang; Shi Ping Yan

doi:10.1107/S0108270101006849

A novel hydrogen-bonded microporous framework constructed from two different metal complexes

En Qing Gao^*
, Dai Zheng Liao
, Zong Hui Jiang
, Shi Ping Yan

^*Corresponding author for this work

Qufu Normal University
Nankai University

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A hydrogen-bonded coordination supramolecule, (meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane- K⁴N)nickel(II) [ N,N-o-phenylenebis(oxamato)-k⁴O,N,N′,O′] nickelate(II) dihydrate, [Ni(C₁₆H₃₆N₄)] [Ni(C₁₀H₄N₂O₆)]·-2H ₂O or [Ni(meso-cth)][Ni(opba)]·2H₂O, has been prepared and characterized by X-ray crystallographic analysis. The two complex ions, i.e. [Ni(meso-cth)]²⁺ and [Ni(opba)]^2-, are hydrogen bonded to each other, resulting in two-dimensional neutral supramolecular sheets. The sheets stack along the a direction to produce a three-dimensional architecture with one-dimensional channels in which hydrogen-bonded chains of water molecules are included.

Original language	English
Pages (from-to)	807-809
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	57
Issue number	7
DOIs	https://doi.org/10.1107/S0108270101006849
State	Published - Jul 2001
Externally published	Yes

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@article{71f62aab2a954ec69aaacf84217db76a,

title = "A novel hydrogen-bonded microporous framework constructed from two different metal complexes",

abstract = "A hydrogen-bonded coordination supramolecule, (meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane- K4N)nickel(II) [ N,N-o-phenylenebis(oxamato)-k4O,N,N′,O′] nickelate(II) dihydrate, [Ni(C16H36N4)] [Ni(C10H4N2O6)]·-2H 2O or [Ni(meso-cth)][Ni(opba)]·2H2O, has been prepared and characterized by X-ray crystallographic analysis. The two complex ions, i.e. [Ni(meso-cth)]2+ and [Ni(opba)]2-, are hydrogen bonded to each other, resulting in two-dimensional neutral supramolecular sheets. The sheets stack along the a direction to produce a three-dimensional architecture with one-dimensional channels in which hydrogen-bonded chains of water molecules are included.",

author = "Gao, \{En Qing\} and Liao, \{Dai Zheng\} and Jiang, \{Zong Hui\} and Yan, \{Shi Ping\}",

year = "2001",

month = jul,

doi = "10.1107/S0108270101006849",

language = "英语",

volume = "57",

pages = "807--809",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "John Wiley \& Sons Inc.",

number = "7",

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TY - JOUR

T1 - A novel hydrogen-bonded microporous framework constructed from two different metal complexes

AU - Gao, En Qing

AU - Liao, Dai Zheng

AU - Jiang, Zong Hui

AU - Yan, Shi Ping

PY - 2001/7

Y1 - 2001/7

N2 - A hydrogen-bonded coordination supramolecule, (meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane- K4N)nickel(II) [ N,N-o-phenylenebis(oxamato)-k4O,N,N′,O′] nickelate(II) dihydrate, [Ni(C16H36N4)] [Ni(C10H4N2O6)]·-2H 2O or [Ni(meso-cth)][Ni(opba)]·2H2O, has been prepared and characterized by X-ray crystallographic analysis. The two complex ions, i.e. [Ni(meso-cth)]2+ and [Ni(opba)]2-, are hydrogen bonded to each other, resulting in two-dimensional neutral supramolecular sheets. The sheets stack along the a direction to produce a three-dimensional architecture with one-dimensional channels in which hydrogen-bonded chains of water molecules are included.

AB - A hydrogen-bonded coordination supramolecule, (meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane- K4N)nickel(II) [ N,N-o-phenylenebis(oxamato)-k4O,N,N′,O′] nickelate(II) dihydrate, [Ni(C16H36N4)] [Ni(C10H4N2O6)]·-2H 2O or [Ni(meso-cth)][Ni(opba)]·2H2O, has been prepared and characterized by X-ray crystallographic analysis. The two complex ions, i.e. [Ni(meso-cth)]2+ and [Ni(opba)]2-, are hydrogen bonded to each other, resulting in two-dimensional neutral supramolecular sheets. The sheets stack along the a direction to produce a three-dimensional architecture with one-dimensional channels in which hydrogen-bonded chains of water molecules are included.

UR - https://www.scopus.com/pages/publications/0035393432

U2 - 10.1107/S0108270101006849

DO - 10.1107/S0108270101006849

M3 - 文章

AN - SCOPUS:0035393432

SN - 0108-2701

VL - 57

SP - 807

EP - 809

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 7

ER -

A novel hydrogen-bonded microporous framework constructed from two different metal complexes

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