TY - JOUR
T1 - A novel hydrogen-bonded microporous framework constructed from two different metal complexes
AU - Gao, En Qing
AU - Liao, Dai Zheng
AU - Jiang, Zong Hui
AU - Yan, Shi Ping
PY - 2001/7
Y1 - 2001/7
N2 - A hydrogen-bonded coordination supramolecule, (meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane- K4N)nickel(II) [ N,N-o-phenylenebis(oxamato)-k4O,N,N′,O′] nickelate(II) dihydrate, [Ni(C16H36N4)] [Ni(C10H4N2O6)]·-2H 2O or [Ni(meso-cth)][Ni(opba)]·2H2O, has been prepared and characterized by X-ray crystallographic analysis. The two complex ions, i.e. [Ni(meso-cth)]2+ and [Ni(opba)]2-, are hydrogen bonded to each other, resulting in two-dimensional neutral supramolecular sheets. The sheets stack along the a direction to produce a three-dimensional architecture with one-dimensional channels in which hydrogen-bonded chains of water molecules are included.
AB - A hydrogen-bonded coordination supramolecule, (meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane- K4N)nickel(II) [ N,N-o-phenylenebis(oxamato)-k4O,N,N′,O′] nickelate(II) dihydrate, [Ni(C16H36N4)] [Ni(C10H4N2O6)]·-2H 2O or [Ni(meso-cth)][Ni(opba)]·2H2O, has been prepared and characterized by X-ray crystallographic analysis. The two complex ions, i.e. [Ni(meso-cth)]2+ and [Ni(opba)]2-, are hydrogen bonded to each other, resulting in two-dimensional neutral supramolecular sheets. The sheets stack along the a direction to produce a three-dimensional architecture with one-dimensional channels in which hydrogen-bonded chains of water molecules are included.
UR - https://www.scopus.com/pages/publications/0035393432
U2 - 10.1107/S0108270101006849
DO - 10.1107/S0108270101006849
M3 - 文章
AN - SCOPUS:0035393432
SN - 0108-2701
VL - 57
SP - 807
EP - 809
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 7
ER -