A new ultramicrosensor for nitric oxide based on electropolymerized film of nickel salen

Lanqun Mao; Yu Tian; Guoyue Shi; Haiying Liu; Litong Jin; K. Yamamoto; Shuguang Tao; Jiye Jin

doi:10.1080/00032719808005280

A new ultramicrosensor for nitric oxide based on electropolymerized film of nickel salen

Lanqun Mao
, Yu Tian
, Guoyue Shi
, Haiying Liu
, Litong Jin^*
, K. Yamamoto
, Shuguang Tao
, Jiye Jin

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

A new amperometric ultramicrosensor for the determination of nitric oxide (NO) is described. The ultramicrosensor, which is based on an electropolymerized film of ethylenebis(salicylideneiminate) nickel [Ni(salen)] and Nafion, shows a low detection limit, high selectivity and sensitivity to NO determination. The oxidation current (measured by a differential pulse amperometric method) is linear with NO concentration ranging from 1.0 x 10^-8 to 4.0x10^-6 mol/L with a calculated detection limit, at a signal to noise ratio of three, equal to 5.0x10^-9 mol/L. Some endogenous electroactive substances in biological tissues, such as dopamine, 5-HT and nitrite do not interfere with NO determination at the concentrations higher than those in biological systems. The ultramicrosensor could be employed for in vivo measurements of NO. The mechanism of the response of the ultramicrosensor to NO is also studied.

Original language	English
Pages (from-to)	1991-2007
Number of pages	17
Journal	Analytical Letters
Volume	31
Issue number	12
DOIs	https://doi.org/10.1080/00032719808005280
State	Published - 1998

Keywords

Chemically modified ultramicroelectrode
Electropolymerization
Ethylenebis(salicylideneiminate) nickel
Nitric oxide

Access to Document

10.1080/00032719808005280

Cite this

@article{1bc7cfc861194a92bd8df946f9b3fadc,

title = "A new ultramicrosensor for nitric oxide based on electropolymerized film of nickel salen",

abstract = "A new amperometric ultramicrosensor for the determination of nitric oxide (NO) is described. The ultramicrosensor, which is based on an electropolymerized film of ethylenebis(salicylideneiminate) nickel [Ni(salen)] and Nafion, shows a low detection limit, high selectivity and sensitivity to NO determination. The oxidation current (measured by a differential pulse amperometric method) is linear with NO concentration ranging from 1.0 x 10-8 to 4.0x10-6 mol/L with a calculated detection limit, at a signal to noise ratio of three, equal to 5.0x10-9 mol/L. Some endogenous electroactive substances in biological tissues, such as dopamine, 5-HT and nitrite do not interfere with NO determination at the concentrations higher than those in biological systems. The ultramicrosensor could be employed for in vivo measurements of NO. The mechanism of the response of the ultramicrosensor to NO is also studied.",

keywords = "Chemically modified ultramicroelectrode, Electropolymerization, Ethylenebis(salicylideneiminate) nickel, Nitric oxide",

author = "Lanqun Mao and Yu Tian and Guoyue Shi and Haiying Liu and Litong Jin and K. Yamamoto and Shuguang Tao and Jiye Jin",

year = "1998",

doi = "10.1080/00032719808005280",

language = "英语",

volume = "31",

pages = "1991--2007",

journal = "Analytical Letters",

issn = "0003-2719",

publisher = "Taylor and Francis Ltd.",

number = "12",

}

TY - JOUR

T1 - A new ultramicrosensor for nitric oxide based on electropolymerized film of nickel salen

AU - Mao, Lanqun

AU - Tian, Yu

AU - Shi, Guoyue

AU - Liu, Haiying

AU - Jin, Litong

AU - Yamamoto, K.

AU - Tao, Shuguang

AU - Jin, Jiye

PY - 1998

Y1 - 1998

N2 - A new amperometric ultramicrosensor for the determination of nitric oxide (NO) is described. The ultramicrosensor, which is based on an electropolymerized film of ethylenebis(salicylideneiminate) nickel [Ni(salen)] and Nafion, shows a low detection limit, high selectivity and sensitivity to NO determination. The oxidation current (measured by a differential pulse amperometric method) is linear with NO concentration ranging from 1.0 x 10-8 to 4.0x10-6 mol/L with a calculated detection limit, at a signal to noise ratio of three, equal to 5.0x10-9 mol/L. Some endogenous electroactive substances in biological tissues, such as dopamine, 5-HT and nitrite do not interfere with NO determination at the concentrations higher than those in biological systems. The ultramicrosensor could be employed for in vivo measurements of NO. The mechanism of the response of the ultramicrosensor to NO is also studied.

AB - A new amperometric ultramicrosensor for the determination of nitric oxide (NO) is described. The ultramicrosensor, which is based on an electropolymerized film of ethylenebis(salicylideneiminate) nickel [Ni(salen)] and Nafion, shows a low detection limit, high selectivity and sensitivity to NO determination. The oxidation current (measured by a differential pulse amperometric method) is linear with NO concentration ranging from 1.0 x 10-8 to 4.0x10-6 mol/L with a calculated detection limit, at a signal to noise ratio of three, equal to 5.0x10-9 mol/L. Some endogenous electroactive substances in biological tissues, such as dopamine, 5-HT and nitrite do not interfere with NO determination at the concentrations higher than those in biological systems. The ultramicrosensor could be employed for in vivo measurements of NO. The mechanism of the response of the ultramicrosensor to NO is also studied.

KW - Chemically modified ultramicroelectrode

KW - Electropolymerization

KW - Ethylenebis(salicylideneiminate) nickel

KW - Nitric oxide

UR - https://www.scopus.com/pages/publications/0031655389

U2 - 10.1080/00032719808005280

DO - 10.1080/00032719808005280

M3 - 文章

AN - SCOPUS:0031655389

SN - 0003-2719

VL - 31

SP - 1991

EP - 2007

JO - Analytical Letters

JF - Analytical Letters

IS - 12

ER -

A new ultramicrosensor for nitric oxide based on electropolymerized film of nickel salen

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this