A new UiO-66-NH2 based mixed-matrix membranes with high CO2/CH4 separation performance

Yunzhe Jiang; Chuanyao Liu; Jürgen Caro; Aisheng Huang

doi:10.1016/j.micromeso.2018.08.003

A new UiO-66-NH₂ based mixed-matrix membranes with high CO₂/CH₄ separation performance

Yunzhe Jiang
, Chuanyao Liu
, Jürgen Caro
, Aisheng Huang^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

193 Scopus citations

Abstract

A new UiO-66-NH₂ based MOF named UiO-66-NH₂@ICA has been prepared by grafting imidazole-2-carbaldehyde (ICA) to UiO-66-NH₂ through a post-synthesis reaction via amine condensation. FESEM, XRD, ¹H NMR, FT-IR and N₂ adsorption were used to characterize the morphology and structure of UiO-66-NH₂@ICA. The grafted ICA mainly reduces the pore volume of UiO-66-NH₂ but increases the number of nitrogen atom as binding site of CO₂. The UiO-66-NH₂@ICA showed less BET surface area but a higher CO₂/CH₄ adsorption selectivity in comparison with UiO-66-NH₂. UiO-66-NH₂@ICA and UiO-66-NH₂ crystals were dispersed in Matrimid^®5218 to form mixed-matrix membranes (MMMs). Single gas permeation and mixed gas separation was carried out to investigate the effects of filler loading and feed gas pressure on the separation performances of the MMMs. The UiO-66-NH₂@ICA/Matrimid^® MMM with 10 wt % filler showed a high CO₂/CH₄ selectivity with a separation factor of 64.7, which is an increase by 40% in comparison with UiO-66-NH₂/Matrimid^® MMM.

Original language	English
Pages (from-to)	203-211
Number of pages	9
Journal	Microporous and Mesoporous Materials
Volume	274
DOIs	https://doi.org/10.1016/j.micromeso.2018.08.003
State	Published - 15 Jan 2019

Keywords

CO/CH separation
Imidazole-2-carbaldehyde
Mixed-matrix membranes
N as CO adsorption site
UiO-66-NH

Access to Document

10.1016/j.micromeso.2018.08.003

Cite this

@article{07be046054214df4913534ae4e2a6952,

title = "A new UiO-66-NH2 based mixed-matrix membranes with high CO2/CH4 separation performance",

abstract = "A new UiO-66-NH2 based MOF named UiO-66-NH2@ICA has been prepared by grafting imidazole-2-carbaldehyde (ICA) to UiO-66-NH2 through a post-synthesis reaction via amine condensation. FESEM, XRD, 1H NMR, FT-IR and N2 adsorption were used to characterize the morphology and structure of UiO-66-NH2@ICA. The grafted ICA mainly reduces the pore volume of UiO-66-NH2 but increases the number of nitrogen atom as binding site of CO2. The UiO-66-NH2@ICA showed less BET surface area but a higher CO2/CH4 adsorption selectivity in comparison with UiO-66-NH2. UiO-66-NH2@ICA and UiO-66-NH2 crystals were dispersed in Matrimid{\textregistered}5218 to form mixed-matrix membranes (MMMs). Single gas permeation and mixed gas separation was carried out to investigate the effects of filler loading and feed gas pressure on the separation performances of the MMMs. The UiO-66-NH2@ICA/Matrimid{\textregistered} MMM with 10 wt \% filler showed a high CO2/CH4 selectivity with a separation factor of 64.7, which is an increase by 40\% in comparison with UiO-66-NH2/Matrimid{\textregistered} MMM.",

keywords = "CO/CH separation, Imidazole-2-carbaldehyde, Mixed-matrix membranes, N as CO adsorption site, UiO-66-NH",

author = "Yunzhe Jiang and Chuanyao Liu and J{\"u}rgen Caro and Aisheng Huang",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier Inc.",

year = "2019",

month = jan,

day = "15",

doi = "10.1016/j.micromeso.2018.08.003",

language = "英语",

volume = "274",

pages = "203--211",

journal = "Microporous and Mesoporous Materials",

issn = "1387-1811",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - A new UiO-66-NH2 based mixed-matrix membranes with high CO2/CH4 separation performance

AU - Jiang, Yunzhe

AU - Liu, Chuanyao

AU - Caro, Jürgen

AU - Huang, Aisheng

PY - 2019/1/15

Y1 - 2019/1/15

N2 - A new UiO-66-NH2 based MOF named UiO-66-NH2@ICA has been prepared by grafting imidazole-2-carbaldehyde (ICA) to UiO-66-NH2 through a post-synthesis reaction via amine condensation. FESEM, XRD, 1H NMR, FT-IR and N2 adsorption were used to characterize the morphology and structure of UiO-66-NH2@ICA. The grafted ICA mainly reduces the pore volume of UiO-66-NH2 but increases the number of nitrogen atom as binding site of CO2. The UiO-66-NH2@ICA showed less BET surface area but a higher CO2/CH4 adsorption selectivity in comparison with UiO-66-NH2. UiO-66-NH2@ICA and UiO-66-NH2 crystals were dispersed in Matrimid®5218 to form mixed-matrix membranes (MMMs). Single gas permeation and mixed gas separation was carried out to investigate the effects of filler loading and feed gas pressure on the separation performances of the MMMs. The UiO-66-NH2@ICA/Matrimid® MMM with 10 wt % filler showed a high CO2/CH4 selectivity with a separation factor of 64.7, which is an increase by 40% in comparison with UiO-66-NH2/Matrimid® MMM.

AB - A new UiO-66-NH2 based MOF named UiO-66-NH2@ICA has been prepared by grafting imidazole-2-carbaldehyde (ICA) to UiO-66-NH2 through a post-synthesis reaction via amine condensation. FESEM, XRD, 1H NMR, FT-IR and N2 adsorption were used to characterize the morphology and structure of UiO-66-NH2@ICA. The grafted ICA mainly reduces the pore volume of UiO-66-NH2 but increases the number of nitrogen atom as binding site of CO2. The UiO-66-NH2@ICA showed less BET surface area but a higher CO2/CH4 adsorption selectivity in comparison with UiO-66-NH2. UiO-66-NH2@ICA and UiO-66-NH2 crystals were dispersed in Matrimid®5218 to form mixed-matrix membranes (MMMs). Single gas permeation and mixed gas separation was carried out to investigate the effects of filler loading and feed gas pressure on the separation performances of the MMMs. The UiO-66-NH2@ICA/Matrimid® MMM with 10 wt % filler showed a high CO2/CH4 selectivity with a separation factor of 64.7, which is an increase by 40% in comparison with UiO-66-NH2/Matrimid® MMM.

KW - CO/CH separation

KW - Imidazole-2-carbaldehyde

KW - Mixed-matrix membranes

KW - N as CO adsorption site

KW - UiO-66-NH

UR - https://www.scopus.com/pages/publications/85051144560

U2 - 10.1016/j.micromeso.2018.08.003

DO - 10.1016/j.micromeso.2018.08.003

M3 - 文章

AN - SCOPUS:85051144560

SN - 1387-1811

VL - 274

SP - 203

EP - 211

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

ER -

A new UiO-66-NH₂ based mixed-matrix membranes with high CO₂/CH₄ separation performance

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this