A neutral branched platinum-acetylide complex possessing a tetraphenylethylene core: preparation of a luminescent organometallic gelator and its unexpected spectroscopic behaviour during sol-to-gel transition

Yuan Yuan Ren; Nai Wei Wu; Junhai Huang; Zheng Xu; Dan Dan Sun; Cui Hong Wang; Lin Xu

doi:10.1039/c5cc04789g

A neutral branched platinum-acetylide complex possessing a tetraphenylethylene core: preparation of a luminescent organometallic gelator and its unexpected spectroscopic behaviour during sol-to-gel transition

Yuan Yuan Ren
, Nai Wei Wu
, Junhai Huang
, Zheng Xu
, Dan Dan Sun
, Cui Hong Wang^*
, Lin Xu

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

A neutral branched platinum-acetylide complex TPA possessing a tetraphenylethylene core was successfully prepared, which was found to form luminescent organometallic gels in ethyl acetate. Stimulated by temperature or F^-, the reversible gel-sol transition was realized. More interestingly, TPA exhibited an unexpected blue shift of the emission during the sol-to-gel transition.

Original language	English
Pages (from-to)	15153-15156
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	82
DOIs	https://doi.org/10.1039/c5cc04789g
State	Published - 20 Aug 2015

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Ren, Y. Y., Wu, N. W., Huang, J., Xu, Z., Sun, D. D., Wang, C. H., & Xu, L. (2015). A neutral branched platinum-acetylide complex possessing a tetraphenylethylene core: preparation of a luminescent organometallic gelator and its unexpected spectroscopic behaviour during sol-to-gel transition. Chemical Communications, 51(82), 15153-15156. https://doi.org/10.1039/c5cc04789g

@article{5878175ca777445ca9121133c9f93a82,

title = "A neutral branched platinum-acetylide complex possessing a tetraphenylethylene core: preparation of a luminescent organometallic gelator and its unexpected spectroscopic behaviour during sol-to-gel transition",

abstract = "A neutral branched platinum-acetylide complex TPA possessing a tetraphenylethylene core was successfully prepared, which was found to form luminescent organometallic gels in ethyl acetate. Stimulated by temperature or F-, the reversible gel-sol transition was realized. More interestingly, TPA exhibited an unexpected blue shift of the emission during the sol-to-gel transition.",

author = "Ren, \{Yuan Yuan\} and Wu, \{Nai Wei\} and Junhai Huang and Zheng Xu and Sun, \{Dan Dan\} and Wang, \{Cui Hong\} and Lin Xu",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2015",

month = aug,

day = "20",

doi = "10.1039/c5cc04789g",

language = "英语",

volume = "51",

pages = "15153--15156",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "82",

}

Ren, YY, Wu, NW, Huang, J, Xu, Z, Sun, DD, Wang, CH & Xu, L 2015, 'A neutral branched platinum-acetylide complex possessing a tetraphenylethylene core: preparation of a luminescent organometallic gelator and its unexpected spectroscopic behaviour during sol-to-gel transition', Chemical Communications, vol. 51, no. 82, pp. 15153-15156. https://doi.org/10.1039/c5cc04789g

A neutral branched platinum-acetylide complex possessing a tetraphenylethylene core: preparation of a luminescent organometallic gelator and its unexpected spectroscopic behaviour during sol-to-gel transition. / Ren, Yuan Yuan; Wu, Nai Wei; Huang, Junhai et al.
In: Chemical Communications, Vol. 51, No. 82, 20.08.2015, p. 15153-15156.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A neutral branched platinum-acetylide complex possessing a tetraphenylethylene core

T2 - preparation of a luminescent organometallic gelator and its unexpected spectroscopic behaviour during sol-to-gel transition

AU - Ren, Yuan Yuan

AU - Wu, Nai Wei

AU - Huang, Junhai

AU - Xu, Zheng

AU - Sun, Dan Dan

AU - Wang, Cui Hong

AU - Xu, Lin

PY - 2015/8/20

Y1 - 2015/8/20

N2 - A neutral branched platinum-acetylide complex TPA possessing a tetraphenylethylene core was successfully prepared, which was found to form luminescent organometallic gels in ethyl acetate. Stimulated by temperature or F-, the reversible gel-sol transition was realized. More interestingly, TPA exhibited an unexpected blue shift of the emission during the sol-to-gel transition.

AB - A neutral branched platinum-acetylide complex TPA possessing a tetraphenylethylene core was successfully prepared, which was found to form luminescent organometallic gels in ethyl acetate. Stimulated by temperature or F-, the reversible gel-sol transition was realized. More interestingly, TPA exhibited an unexpected blue shift of the emission during the sol-to-gel transition.

UR - https://www.scopus.com/pages/publications/84942847909

U2 - 10.1039/c5cc04789g

DO - 10.1039/c5cc04789g

M3 - 文章

AN - SCOPUS:84942847909

SN - 1359-7345

VL - 51

SP - 15153

EP - 15156

JO - Chemical Communications

JF - Chemical Communications

IS - 82

ER -

A neutral branched platinum-acetylide complex possessing a tetraphenylethylene core: preparation of a luminescent organometallic gelator and its unexpected spectroscopic behaviour during sol-to-gel transition

Abstract

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