TY - JOUR
T1 - A neodymium coordination polymer with mixed m-phenylenediacrylate and formate bridges
T2 - Synthesis, unprecedented topology, and magnetism
AU - Sun, Qian
AU - Zhang, Jian Yong
AU - Tian, Hua
AU - Wang, Yan Qin
AU - Gao, En Qing
PY - 2009/5
Y1 - 2009/5
N2 - A new lanthanide(III) coordination polymer with mixed m-phenylenediacrylate (mpda) and formate bridges, [Nd(mpda)(HCOO)(H2O)]n was synthesized by a solvothermal reaction involving the in situ formation of formate from N,N-dimethyl formamide. The three-dimensional metal-organic framework contains μ3-formate-bridged Nd(III) layers pillared by the mpda ligand and exhibits an unprecedented 3,7-connected topology with Schläfli symbol (4,62)2(42,6)(47,64,810). The magnetic properties are typical of the Nd(III) 4I9/2 ground state perturbed by ligand field and probable antiferromagnetic exchange through triple μ2-oxygen bridges.
AB - A new lanthanide(III) coordination polymer with mixed m-phenylenediacrylate (mpda) and formate bridges, [Nd(mpda)(HCOO)(H2O)]n was synthesized by a solvothermal reaction involving the in situ formation of formate from N,N-dimethyl formamide. The three-dimensional metal-organic framework contains μ3-formate-bridged Nd(III) layers pillared by the mpda ligand and exhibits an unprecedented 3,7-connected topology with Schläfli symbol (4,62)2(42,6)(47,64,810). The magnetic properties are typical of the Nd(III) 4I9/2 ground state perturbed by ligand field and probable antiferromagnetic exchange through triple μ2-oxygen bridges.
KW - Coordination polymer
KW - Lanthanide
KW - Magnetic properties
KW - Solvothermal synthesis
UR - https://www.scopus.com/pages/publications/67349146973
U2 - 10.1016/j.inoche.2009.03.002
DO - 10.1016/j.inoche.2009.03.002
M3 - 文章
AN - SCOPUS:67349146973
SN - 1387-7003
VL - 12
SP - 426
EP - 429
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 5
ER -