A neodymium coordination polymer with mixed m-phenylenediacrylate and formate bridges: Synthesis, unprecedented topology, and magnetism

Qian Sun; Jian Yong Zhang; Hua Tian; Yan Qin Wang; En Qing Gao

doi:10.1016/j.inoche.2009.03.002

A neodymium coordination polymer with mixed m-phenylenediacrylate and formate bridges: Synthesis, unprecedented topology, and magnetism

Qian Sun
, Jian Yong Zhang
, Hua Tian
, Yan Qin Wang
, En Qing Gao^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

A new lanthanide(III) coordination polymer with mixed m-phenylenediacrylate (mpda) and formate bridges, [Nd(mpda)(HCOO)(H₂O)]_n was synthesized by a solvothermal reaction involving the in situ formation of formate from N,N-dimethyl formamide. The three-dimensional metal-organic framework contains μ₃-formate-bridged Nd(III) layers pillared by the mpda ligand and exhibits an unprecedented 3,7-connected topology with Schläfli symbol (4,6²)₂(4²,6)(4⁷,6⁴,8¹⁰). The magnetic properties are typical of the Nd(III) ⁴I_9/2 ground state perturbed by ligand field and probable antiferromagnetic exchange through triple μ₂-oxygen bridges.

Original language	English
Pages (from-to)	426-429
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	12
Issue number	5
DOIs	https://doi.org/10.1016/j.inoche.2009.03.002
State	Published - May 2009

Keywords

Coordination polymer
Lanthanide
Magnetic properties
Solvothermal synthesis

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10.1016/j.inoche.2009.03.002

Cite this

@article{0d53ca0fb9634cbd82b846b595c1b638,

title = "A neodymium coordination polymer with mixed m-phenylenediacrylate and formate bridges: Synthesis, unprecedented topology, and magnetism",

abstract = "A new lanthanide(III) coordination polymer with mixed m-phenylenediacrylate (mpda) and formate bridges, [Nd(mpda)(HCOO)(H2O)]n was synthesized by a solvothermal reaction involving the in situ formation of formate from N,N-dimethyl formamide. The three-dimensional metal-organic framework contains μ3-formate-bridged Nd(III) layers pillared by the mpda ligand and exhibits an unprecedented 3,7-connected topology with Schl{\"a}fli symbol (4,62)2(42,6)(47,64,810). The magnetic properties are typical of the Nd(III) 4I9/2 ground state perturbed by ligand field and probable antiferromagnetic exchange through triple μ2-oxygen bridges.",

keywords = "Coordination polymer, Lanthanide, Magnetic properties, Solvothermal synthesis",

author = "Qian Sun and Zhang, \{Jian Yong\} and Hua Tian and Wang, \{Yan Qin\} and Gao, \{En Qing\}",

year = "2009",

month = may,

doi = "10.1016/j.inoche.2009.03.002",

language = "英语",

volume = "12",

pages = "426--429",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "5",

}

TY - JOUR

T1 - A neodymium coordination polymer with mixed m-phenylenediacrylate and formate bridges

T2 - Synthesis, unprecedented topology, and magnetism

AU - Sun, Qian

AU - Zhang, Jian Yong

AU - Tian, Hua

AU - Wang, Yan Qin

AU - Gao, En Qing

PY - 2009/5

Y1 - 2009/5

N2 - A new lanthanide(III) coordination polymer with mixed m-phenylenediacrylate (mpda) and formate bridges, [Nd(mpda)(HCOO)(H2O)]n was synthesized by a solvothermal reaction involving the in situ formation of formate from N,N-dimethyl formamide. The three-dimensional metal-organic framework contains μ3-formate-bridged Nd(III) layers pillared by the mpda ligand and exhibits an unprecedented 3,7-connected topology with Schläfli symbol (4,62)2(42,6)(47,64,810). The magnetic properties are typical of the Nd(III) 4I9/2 ground state perturbed by ligand field and probable antiferromagnetic exchange through triple μ2-oxygen bridges.

AB - A new lanthanide(III) coordination polymer with mixed m-phenylenediacrylate (mpda) and formate bridges, [Nd(mpda)(HCOO)(H2O)]n was synthesized by a solvothermal reaction involving the in situ formation of formate from N,N-dimethyl formamide. The three-dimensional metal-organic framework contains μ3-formate-bridged Nd(III) layers pillared by the mpda ligand and exhibits an unprecedented 3,7-connected topology with Schläfli symbol (4,62)2(42,6)(47,64,810). The magnetic properties are typical of the Nd(III) 4I9/2 ground state perturbed by ligand field and probable antiferromagnetic exchange through triple μ2-oxygen bridges.

KW - Coordination polymer

KW - Lanthanide

KW - Magnetic properties

KW - Solvothermal synthesis

UR - https://www.scopus.com/pages/publications/67349146973

U2 - 10.1016/j.inoche.2009.03.002

DO - 10.1016/j.inoche.2009.03.002

M3 - 文章

AN - SCOPUS:67349146973

SN - 1387-7003

VL - 12

SP - 426

EP - 429

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 5

ER -

A neodymium coordination polymer with mixed m-phenylenediacrylate and formate bridges: Synthesis, unprecedented topology, and magnetism

Abstract

Keywords

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