A hybrid P,N-Ligand functionalized imidazolium salt for palladium-catalyzed heck reactions in ionic liquid solution

Qing Xia Wan; Ye Liu; Yue Qin Cai

doi:10.1007/s10562-008-9700-5

A hybrid P,N-Ligand functionalized imidazolium salt for palladium-catalyzed heck reactions in ionic liquid solution

Qing Xia Wan
, Ye Liu^*
, Yue Qin Cai

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

A hybrid P,N-donor functionalized imidazolium salt has been synthesized and investigated as a ligand for the palladium catalyzed Heck reaction. Due to the advantageous features of this hybrid P,N-donor like the hemilabile ligation to Pd center, the improved oxidation tolerance and the ionophilicity, the derived palladium catalyst served as an efficient, stable and recyclable system even after seven reuses.

Original language	English
Pages (from-to)	386-391
Number of pages	6
Journal	Catalysis Letters
Volume	127
Issue number	3-4
DOIs	https://doi.org/10.1007/s10562-008-9700-5
State	Published - Feb 2009

Keywords

Heck reactions
Hybrid ligands
Imidazolium salts
Ionic liquids

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title = "A hybrid P,N-Ligand functionalized imidazolium salt for palladium-catalyzed heck reactions in ionic liquid solution",

abstract = "A hybrid P,N-donor functionalized imidazolium salt has been synthesized and investigated as a ligand for the palladium catalyzed Heck reaction. Due to the advantageous features of this hybrid P,N-donor like the hemilabile ligation to Pd center, the improved oxidation tolerance and the ionophilicity, the derived palladium catalyst served as an efficient, stable and recyclable system even after seven reuses.",

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AU - Wan, Qing Xia

AU - Liu, Ye

AU - Cai, Yue Qin

PY - 2009/2

Y1 - 2009/2

N2 - A hybrid P,N-donor functionalized imidazolium salt has been synthesized and investigated as a ligand for the palladium catalyzed Heck reaction. Due to the advantageous features of this hybrid P,N-donor like the hemilabile ligation to Pd center, the improved oxidation tolerance and the ionophilicity, the derived palladium catalyst served as an efficient, stable and recyclable system even after seven reuses.

AB - A hybrid P,N-donor functionalized imidazolium salt has been synthesized and investigated as a ligand for the palladium catalyzed Heck reaction. Due to the advantageous features of this hybrid P,N-donor like the hemilabile ligation to Pd center, the improved oxidation tolerance and the ionophilicity, the derived palladium catalyst served as an efficient, stable and recyclable system even after seven reuses.

KW - Heck reactions

KW - Hybrid ligands

KW - Imidazolium salts

KW - Ionic liquids

UR - https://www.scopus.com/pages/publications/58349095731

U2 - 10.1007/s10562-008-9700-5

DO - 10.1007/s10562-008-9700-5

M3 - 文章

AN - SCOPUS:58349095731

SN - 1011-372X

VL - 127

SP - 386

EP - 391

JO - Catalysis Letters

JF - Catalysis Letters

IS - 3-4

ER -

A hybrid P,N-Ligand functionalized imidazolium salt for palladium-catalyzed heck reactions in ionic liquid solution

Abstract

Keywords

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