A highly selective solid-contact electrode for Ag + based on a monoazathiacrown ether ionophore

Shun Yang Yu; Lan Ju; Fu Hai Li; Yong Ming Liu; Jun Feng Fang

doi:10.1016/j.cclet.2011.12.016

A highly selective solid-contact electrode for Ag ⁺ based on a monoazathiacrown ether ionophore

Shun Yang Yu^*
, Lan Ju
, Fu Hai Li
, Yong Ming Liu
, Jun Feng Fang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A new solid-contact Ag ⁺-selective electrode was prepared with 9,10,12,13,24,25-hexahydro-5H,15H,23H-dibenzo[b,q][1,7,10,13,19,4,16] -entathiadiazacyclodocosine-6,16(7H,17H)-dione as ionophore, and α,ω-dihexylsexithiophene (DH-6T) ion-to-electron transducer. The sensor exhibited a working concentration range of 10 ^-8 to 10 ^-3 mol/L, with a near-Nernstian slope of 55.1 ± 0.2 mV/dec and detection limit of 1.7 × 10 ^-9 mol/L. The fabricated electrodes demonstrated excellent selectivity over the most common monovalent and divalent cations.

Original language	English
Pages (from-to)	488-491
Number of pages	4
Journal	Chinese Chemical Letters
Volume	23
Issue number	4
DOIs	https://doi.org/10.1016/j.cclet.2011.12.016
State	Published - Apr 2012
Externally published	Yes

Keywords

Ion-selective electrodes
Low detection limit
Silver
Solid contact

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10.1016/j.cclet.2011.12.016

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title = "A highly selective solid-contact electrode for Ag + based on a monoazathiacrown ether ionophore",

abstract = "A new solid-contact Ag +-selective electrode was prepared with 9,10,12,13,24,25-hexahydro-5H,15H,23H-dibenzo[b,q][1,7,10,13,19,4,16] -entathiadiazacyclodocosine-6,16(7H,17H)-dione as ionophore, and α,ω-dihexylsexithiophene (DH-6T) ion-to-electron transducer. The sensor exhibited a working concentration range of 10 -8 to 10 -3 mol/L, with a near-Nernstian slope of 55.1 ± 0.2 mV/dec and detection limit of 1.7 × 10 -9 mol/L. The fabricated electrodes demonstrated excellent selectivity over the most common monovalent and divalent cations.",

keywords = "Ion-selective electrodes, Low detection limit, Silver, Solid contact",

author = "Yu, \{Shun Yang\} and Lan Ju and Li, \{Fu Hai\} and Liu, \{Yong Ming\} and Fang, \{Jun Feng\}",

year = "2012",

month = apr,

doi = "10.1016/j.cclet.2011.12.016",

language = "英语",

volume = "23",

pages = "488--491",

journal = "Chinese Chemical Letters",

issn = "1001-8417",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - A highly selective solid-contact electrode for Ag + based on a monoazathiacrown ether ionophore

AU - Yu, Shun Yang

AU - Ju, Lan

AU - Li, Fu Hai

AU - Liu, Yong Ming

AU - Fang, Jun Feng

PY - 2012/4

Y1 - 2012/4

N2 - A new solid-contact Ag +-selective electrode was prepared with 9,10,12,13,24,25-hexahydro-5H,15H,23H-dibenzo[b,q][1,7,10,13,19,4,16] -entathiadiazacyclodocosine-6,16(7H,17H)-dione as ionophore, and α,ω-dihexylsexithiophene (DH-6T) ion-to-electron transducer. The sensor exhibited a working concentration range of 10 -8 to 10 -3 mol/L, with a near-Nernstian slope of 55.1 ± 0.2 mV/dec and detection limit of 1.7 × 10 -9 mol/L. The fabricated electrodes demonstrated excellent selectivity over the most common monovalent and divalent cations.

AB - A new solid-contact Ag +-selective electrode was prepared with 9,10,12,13,24,25-hexahydro-5H,15H,23H-dibenzo[b,q][1,7,10,13,19,4,16] -entathiadiazacyclodocosine-6,16(7H,17H)-dione as ionophore, and α,ω-dihexylsexithiophene (DH-6T) ion-to-electron transducer. The sensor exhibited a working concentration range of 10 -8 to 10 -3 mol/L, with a near-Nernstian slope of 55.1 ± 0.2 mV/dec and detection limit of 1.7 × 10 -9 mol/L. The fabricated electrodes demonstrated excellent selectivity over the most common monovalent and divalent cations.

KW - Ion-selective electrodes

KW - Low detection limit

KW - Silver

KW - Solid contact

UR - https://www.scopus.com/pages/publications/84862829012

U2 - 10.1016/j.cclet.2011.12.016

DO - 10.1016/j.cclet.2011.12.016

M3 - 文章

AN - SCOPUS:84862829012

SN - 1001-8417

VL - 23

SP - 488

EP - 491

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 4

ER -

A highly selective solid-contact electrode for Ag ⁺ based on a monoazathiacrown ether ionophore

Abstract

Keywords

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