TY - JOUR
T1 - A highly efficient procedure for the oxathioacetalization of carbonyl compounds under solvent-free conditions
AU - Liang, Xuezheng
AU - Chen, Lu
AU - Wu, Haihong
AU - Yang, Jianguo
AU - He, Mingyuan
PY - 2009/12
Y1 - 2009/12
N2 - The novel efficient procedure has been developed for the oxathioacetalization of carbonyl compounds and 2-mercaptoethanol using the novel carbon-based sulfonic acid as catalyst under solvent-free condition at room temperature. The results showed that the novel catalyst was very efficient for the reactions with good to excellent yields in short time. The novel catalyst owned many advantages such as operational simplicity, without need of any solvent, small amount of usage, low cost of the catalyst used, high yields, applicability to large-scale reactions, reusability and chemoselectivity over the traditional catalysts, which made the catalyst one of the best choices for the reactions.
AB - The novel efficient procedure has been developed for the oxathioacetalization of carbonyl compounds and 2-mercaptoethanol using the novel carbon-based sulfonic acid as catalyst under solvent-free condition at room temperature. The results showed that the novel catalyst was very efficient for the reactions with good to excellent yields in short time. The novel catalyst owned many advantages such as operational simplicity, without need of any solvent, small amount of usage, low cost of the catalyst used, high yields, applicability to large-scale reactions, reusability and chemoselectivity over the traditional catalysts, which made the catalyst one of the best choices for the reactions.
KW - Catalysis
KW - Chemoselectivity
KW - Efficient
KW - Oxathioacetalization
UR - https://www.scopus.com/pages/publications/75749109813
U2 - 10.1007/s11426-009-0134-8
DO - 10.1007/s11426-009-0134-8
M3 - 文章
AN - SCOPUS:75749109813
SN - 1006-9291
VL - 52
SP - 2166
EP - 2170
JO - Science in China, Series B: Chemistry
JF - Science in China, Series B: Chemistry
IS - 12
ER -