A high-performance dielectric block copolymer with a self-assembled superhelical nanotube morphology

Wenmei Liu; Jie Chen; Dandan Zhou; Xiaojuan Liao; Meiran Xie; Ruyi Sun

doi:10.1039/c6py01571a

A high-performance dielectric block copolymer with a self-assembled superhelical nanotube morphology

Wenmei Liu
, Jie Chen
, Dandan Zhou
, Xiaojuan Liao
, Meiran Xie^*
, Ruyi Sun

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

A block copolymer consisting of functional polynorbornene (PNBE) and polyacetylene (PA) segments was synthesized by tandem metathesis polymerization, and self-assembled into a superhelical nanotube morphology from achiral building blocks. Bearing insulated PNBE and conductive PA segments with unique nanostructures, the block copolymers displayed high dielectric permittivities of 25-29, low dielectric losses of 0.03-0.04, and excellent stored/released energy densities of 2.0-1.9/1.7-1.2 J cm^-3 under the breakdown fields of 270-200 MV m^-1, due to strong dipolar and nanointerfacial polarizations as well as stereoregular chain microstructure contributions. This strategy provided a new way for the development of advanced nanodielectric materials.

Original language	English
Pages (from-to)	725-734
Number of pages	10
Journal	Polymer Chemistry
Volume	8
Issue number	4
DOIs	https://doi.org/10.1039/c6py01571a
State	Published - 28 Jan 2017

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title = "A high-performance dielectric block copolymer with a self-assembled superhelical nanotube morphology",

abstract = "A block copolymer consisting of functional polynorbornene (PNBE) and polyacetylene (PA) segments was synthesized by tandem metathesis polymerization, and self-assembled into a superhelical nanotube morphology from achiral building blocks. Bearing insulated PNBE and conductive PA segments with unique nanostructures, the block copolymers displayed high dielectric permittivities of 25-29, low dielectric losses of 0.03-0.04, and excellent stored/released energy densities of 2.0-1.9/1.7-1.2 J cm-3 under the breakdown fields of 270-200 MV m-1, due to strong dipolar and nanointerfacial polarizations as well as stereoregular chain microstructure contributions. This strategy provided a new way for the development of advanced nanodielectric materials.",

author = "Wenmei Liu and Jie Chen and Dandan Zhou and Xiaojuan Liao and Meiran Xie and Ruyi Sun",

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T1 - A high-performance dielectric block copolymer with a self-assembled superhelical nanotube morphology

AU - Liu, Wenmei

AU - Chen, Jie

AU - Zhou, Dandan

AU - Liao, Xiaojuan

AU - Xie, Meiran

AU - Sun, Ruyi

PY - 2017/1/28

Y1 - 2017/1/28

N2 - A block copolymer consisting of functional polynorbornene (PNBE) and polyacetylene (PA) segments was synthesized by tandem metathesis polymerization, and self-assembled into a superhelical nanotube morphology from achiral building blocks. Bearing insulated PNBE and conductive PA segments with unique nanostructures, the block copolymers displayed high dielectric permittivities of 25-29, low dielectric losses of 0.03-0.04, and excellent stored/released energy densities of 2.0-1.9/1.7-1.2 J cm-3 under the breakdown fields of 270-200 MV m-1, due to strong dipolar and nanointerfacial polarizations as well as stereoregular chain microstructure contributions. This strategy provided a new way for the development of advanced nanodielectric materials.

AB - A block copolymer consisting of functional polynorbornene (PNBE) and polyacetylene (PA) segments was synthesized by tandem metathesis polymerization, and self-assembled into a superhelical nanotube morphology from achiral building blocks. Bearing insulated PNBE and conductive PA segments with unique nanostructures, the block copolymers displayed high dielectric permittivities of 25-29, low dielectric losses of 0.03-0.04, and excellent stored/released energy densities of 2.0-1.9/1.7-1.2 J cm-3 under the breakdown fields of 270-200 MV m-1, due to strong dipolar and nanointerfacial polarizations as well as stereoregular chain microstructure contributions. This strategy provided a new way for the development of advanced nanodielectric materials.

UR - https://www.scopus.com/pages/publications/85010501241

U2 - 10.1039/c6py01571a

DO - 10.1039/c6py01571a

M3 - 文章

AN - SCOPUS:85010501241

SN - 1759-9954

VL - 8

SP - 725

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JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 4

ER -

A high-performance dielectric block copolymer with a self-assembled superhelical nanotube morphology

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