A Hg(ClO4)2 3 3H2O Catalyzed sakurai-hosomi allylation of isatins and isatin ketoimines using allyltrimethylsilane

Zhong Yan Cao; Yan Zhang; Cong Bin Ji; Jian Zhou

doi:10.1021/ol202705g

A Hg(ClO₄)₂ 3 3H₂O Catalyzed sakurai-hosomi allylation of isatins and isatin ketoimines using allyltrimethylsilane

Zhong Yan Cao^*
, Yan Zhang
, Cong Bin Ji
, Jian Zhou

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

104 Scopus citations

Abstract

It is reported that Hg(ClO₄)₂ 3 3H₂O could efficiently activate the cheap but less reactive allyltrimethylsilane for the allylation of isatins or isatin ketoimines, with catalyst loading down to 0.1 mol %. This is the first example of Sakurai-Hosomi allylation of ketoimines using allyltrimethylsilane. A rare example of chiral mercury catalysis is also reported.

Original language	English
Pages (from-to)	6398-6401
Number of pages	4
Journal	Organic Letters
Volume	13
Issue number	24
DOIs	https://doi.org/10.1021/ol202705g
State	Published - 16 Dec 2011

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title = "A Hg(ClO4)2 3 3H2O Catalyzed sakurai-hosomi allylation of isatins and isatin ketoimines using allyltrimethylsilane",

abstract = "It is reported that Hg(ClO4)2 3 3H2O could efficiently activate the cheap but less reactive allyltrimethylsilane for the allylation of isatins or isatin ketoimines, with catalyst loading down to 0.1 mol \%. This is the first example of Sakurai-Hosomi allylation of ketoimines using allyltrimethylsilane. A rare example of chiral mercury catalysis is also reported.",

author = "Cao, \{Zhong Yan\} and Yan Zhang and Ji, \{Cong Bin\} and Jian Zhou",

year = "2011",

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journal = "Organic Letters",

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AU - Cao, Zhong Yan

AU - Zhang, Yan

AU - Ji, Cong Bin

AU - Zhou, Jian

PY - 2011/12/16

Y1 - 2011/12/16

N2 - It is reported that Hg(ClO4)2 3 3H2O could efficiently activate the cheap but less reactive allyltrimethylsilane for the allylation of isatins or isatin ketoimines, with catalyst loading down to 0.1 mol %. This is the first example of Sakurai-Hosomi allylation of ketoimines using allyltrimethylsilane. A rare example of chiral mercury catalysis is also reported.

AB - It is reported that Hg(ClO4)2 3 3H2O could efficiently activate the cheap but less reactive allyltrimethylsilane for the allylation of isatins or isatin ketoimines, with catalyst loading down to 0.1 mol %. This is the first example of Sakurai-Hosomi allylation of ketoimines using allyltrimethylsilane. A rare example of chiral mercury catalysis is also reported.

UR - https://www.scopus.com/pages/publications/84055200425

U2 - 10.1021/ol202705g

DO - 10.1021/ol202705g

M3 - 文章

AN - SCOPUS:84055200425

SN - 1523-7060

VL - 13

SP - 6398

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JO - Organic Letters

JF - Organic Letters

IS - 24

ER -

A Hg(ClO₄)₂ 3 3H₂O Catalyzed sakurai-hosomi allylation of isatins and isatin ketoimines using allyltrimethylsilane

Abstract

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