A catalytic enantioselective tandem allylation strategy for rapid terpene construction: Application to the synthesis of pumilaside aglycon

Grace E. Ferris; Kai Hong; Ian A. Roundtree; James P. Morken

doi:10.1021/ja400506j

A catalytic enantioselective tandem allylation strategy for rapid terpene construction: Application to the synthesis of pumilaside aglycon

Grace E. Ferris
, Kai Hong
, Ian A. Roundtree
, James P. Morken^*

^*Corresponding author for this work

Boston College

Research output: Contribution to journal › Article › peer-review

79 Scopus citations

Abstract

Catalytic enantioselective 1,2-diboration of 1,3-dienes followed by cascade allylborations with dicarbonyls provides rapid entry into carbocyclic reaction products. The stereochemical course of this reaction was studied along with its application in the synthesis of pumilaside aglycon.

Original language	English
Pages (from-to)	2501-2504
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	7
DOIs	https://doi.org/10.1021/ja400506j
State	Published - 20 Feb 2013
Externally published	Yes

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title = "A catalytic enantioselective tandem allylation strategy for rapid terpene construction: Application to the synthesis of pumilaside aglycon",

abstract = "Catalytic enantioselective 1,2-diboration of 1,3-dienes followed by cascade allylborations with dicarbonyls provides rapid entry into carbocyclic reaction products. The stereochemical course of this reaction was studied along with its application in the synthesis of pumilaside aglycon.",

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AU - Ferris, Grace E.

AU - Hong, Kai

AU - Roundtree, Ian A.

AU - Morken, James P.

PY - 2013/2/20

Y1 - 2013/2/20

N2 - Catalytic enantioselective 1,2-diboration of 1,3-dienes followed by cascade allylborations with dicarbonyls provides rapid entry into carbocyclic reaction products. The stereochemical course of this reaction was studied along with its application in the synthesis of pumilaside aglycon.

AB - Catalytic enantioselective 1,2-diboration of 1,3-dienes followed by cascade allylborations with dicarbonyls provides rapid entry into carbocyclic reaction products. The stereochemical course of this reaction was studied along with its application in the synthesis of pumilaside aglycon.

UR - https://www.scopus.com/pages/publications/84874102435

U2 - 10.1021/ja400506j

DO - 10.1021/ja400506j

M3 - 文章

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AN - SCOPUS:84874102435

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 7

ER -

A catalytic enantioselective tandem allylation strategy for rapid terpene construction: Application to the synthesis of pumilaside aglycon

Abstract

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