Abstract
A novel 3D Co(ii) coordination polymer, [Co6(4-ptz)6(N3)6]n (1) (4-ptz = 4-(pyridinyl)tetrazole), was synthesized by in situ hydrothermal reaction and characterized magnetically. Compound 1 consists of ferrimagnetic-like Co(ii) layers with the title heterobridges and exhibits the spin-glass slow dynamics. The study on spin-glass behavior in mixed azide and tetrazolate bridged compounds is the first example.
| Original language | English |
|---|---|
| Pages (from-to) | 511-514 |
| Number of pages | 4 |
| Journal | Dalton Transactions |
| Volume | 44 |
| Issue number | 2 |
| DOIs | |
| State | Published - 14 Jan 2015 |