3D Co(ii) coordination polymer with ferrimagnetic-like layers based on azide and tetrazolate bridges showing slow magnetic dynamics

  • Xiu Mei Zhang*
  • , Peng Li
  • , Wei Gao
  • , Jie Ping Liu
  • , En Qing Gao
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

28 Scopus citations

Abstract

A novel 3D Co(ii) coordination polymer, [Co6(4-ptz)6(N3)6]n (1) (4-ptz = 4-(pyridinyl)tetrazole), was synthesized by in situ hydrothermal reaction and characterized magnetically. Compound 1 consists of ferrimagnetic-like Co(ii) layers with the title heterobridges and exhibits the spin-glass slow dynamics. The study on spin-glass behavior in mixed azide and tetrazolate bridged compounds is the first example.

Original languageEnglish
Pages (from-to)511-514
Number of pages4
JournalDalton Transactions
Volume44
Issue number2
DOIs
StatePublished - 14 Jan 2015

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