阿秒符合干涉仪与原子分子及团簇体系阿秒光电子电离延迟测量

The evolution mechanisms of electrons in isolated atoms, molecules and complex systems on a natural timescale have long been a fundamental question in atomic and molecular physics, with significant implications for the applications of quantum materials. Over the past two decades, the development of attosecond light pulses and attosecond metrology has opened new opportunities for investigating the electronic dynamics, while also posing new challenges. Traditional detection techniques, such as time-of-flight and velocity map imaging spectrometers, can be used to study the attosecond scattering phase shifts in the photoemission and ionization processes with extremely high temporal and energy resolution. However, the limitations in multi-particle coincidence detection and three-dimensional momentum correlation limit the deeper exploration of many-body correlations and non-adiabatic ultrafast dynamics involving electron-nuclear coupling. To enable multidimensional and real-time observation of the three-dimensional momenta of both electrons and ions during photoionization, the attosecond interferometry has been integrated into electron-ion coincidence systems. In this study, we utilize an attosecond coincidence interferometer that combines an attosecond pump-infrared femtosecond probe scheme with cold target recoil ion momentum spectroscopy. The apparatus enables attosecond-time-resolved momentum imaging of all charged fragments in atomic and molecular systems, thereby providing deeper insights into the dynamics of photoionization. We also highlight the recent groundbreaking applications and advances of attosecond coincidence interferometer in studying photoionization dynamics in atoms, molecules, and more complex systems.